2-boranatodiphenylphosphanyl-6-phenylphenol

Base Information

• Chemical Name: 2-boranatodiphenylphosphanyl-6-phenylphenol
• CAS No.: 1158430-35-3
• Molecular Formula: C₂₄H₂₂BOP
• Molecular Weight: 368.223
• Mol file: 1158430-35-3.mol

Synonyms:2-boranatodiphenylphosphanyl-6-phenylphenol

Chemical Property of 2-boranatodiphenylphosphanyl-6-phenylphenol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-boranatodiphenylphosphanyl-6-phenylphenol

There total 1 articles about 2-boranatodiphenylphosphanyl-6-phenylphenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C24H21BBrOP (1158430-60-4) → 2-boranatodiphenylphosphanyl-6-phenylphenol (1158430-35-3)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; at 0 ℃; for 2h; Inert atmosphere;

DOI:10.1002/adsc.200800146

Reference yield: 67.0%

2-boranatodiphenylphosphanyl-6-phenylphenol (1158430-35-3) + (S)-[1,1']-binaphthalenyl-2,2'-diol (18531-99-2) → (11bS)-4-((3-(diphenylphosphanyl)-[1,1'-biphenyl]-2-yl)oxy)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine

Guidance literature:

2-boranatodiphenylphosphanyl-6-phenylphenol; With 1,4-diaza-bicyclo[2.2.2]octane; In dichloromethane; at 20 ℃; for 0.166667h; Schlenk technique; Inert atmosphere;

With phosphorus trichloride; In dichloromethane; at 0 - 20 ℃; for 4h; Schlenk technique; Inert atmosphere;

(S)-[1,1']-binaphthalenyl-2,2'-diol; In dichloromethane; at 0 - 20 ℃; for 21h; Schlenk technique; Inert atmosphere;

DOI:10.1002/chem.201800042

Reference yield: 59.0%

2-boranatodiphenylphosphanyl-6-phenylphenol (1158430-35-3) + para-F-TADDOL (144109-63-7) → (3aR,8aR)-6-(3-diphenylphosphanylbiphenyl-2-yloxy)-2,2-dimethyl-4,4,8,8-tetra(4-fluorophenyl)tetrahydro[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine (1354707-27-9)

Guidance literature:

2-boranatodiphenylphosphanyl-6-phenylphenol; With 1,4-diaza-bicyclo[2.2.2]octane; In dichloromethane; at 20 ℃; for 0.166667h; Inert atmosphere;

With phosphorus trichloride; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

para-F-TADDOL; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/adsc.201100658

upstream raw materials:

C₂₄H₂₁BBrOP

Downstream raw materials:

(3aR,8aR)-6-((3-(diphenylphosphanyl)[1,1'-biphenyl]-2-yl)oxy)-2,2-dimethyl-4,4,8,8-tetraphenyltetrahydro[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine

(3aR,8aR)-6-(3-diphenylphosphanylbiphenyl-2-yloxy)-2,2-dimethyl-4,4,8,8-tetra(4-fluorophenyl)tetrahydro[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine

(2R,3R,4aR,9aR)-7-(3-(diphenylphosphino)biphenyl-2-yloxy)-2,3-dimethoxy-2,3-dimethyl-5,5,9,9-tetraphenylhexahydro[1,4]dioxino[2,3-e][1,3,2]dioxaphosphepine

(4S,5S)-4,5-bis{[3-(diphenylphosphanyl)biphenyl-2-yloxy]methyl}-2,2-dimethyl-1,3-dioxolane