144109-63-7

Basic information

• Product Name: para-F-TADDOL
• Synonyms: para-F-TADDOL
• CAS NO: 144109-63-7
• Molecular Weight: 538.539
• Mol File: 144109-63-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: para-F-TADDOL(CAS DataBase Reference)
• NIST Chemistry Reference: para-F-TADDOL(144109-63-7)
• EPA Substance Registry System: para-F-TADDOL(144109-63-7)

Safety Data

• Hazardous Substances Data: 144109-63-7(Hazardous Substances Data)

Upstream product

• 37031-29-1 (-)-dimethy-2,3-O-isopropylidene-L-tartrate 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 59779-75-8 diethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate 
• 352-13-6 4-flourophenylmagnesium bromide 

Downstream Products

• 1354707-27-9 (3aR,8aR)-6-(3-diphenylphosphanylbiphenyl-2-yloxy)-2,2-dimethyl-4,4,8,8-tetra(4-fluorophenyl)tetrahydro[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine 
• 1352731-60-2 Br^(1-)*C₃₇H₃₆F₄NO₂⁽¹⁺⁾ 
• 1352731-53-3 C₃₃H₂₉F₄NO₂ 
• 1352731-44-2 C₃₃H₂₄F₄N₂O₂ 

Relevant articles and documents

Highly enantioselective nickel-catalyzed hydrocyanation of disubstituted methylenecyclopropanes enabled by taddol-based diphosphite ligands

A vast range of novel TADDOL-based diphosphite ligands were first synthesized and applied in the nickel-catalyzed asymmetric hydrocyanation of disubstituted methylenecyclopropanes. By employing these new catalysts, the conversion of diverse methylenecyclo

Synthesis of β-Lactams by Palladium(0)-Catalyzed C(sp3)?H Carbamoylation

A general and user-friendly synthesis of β-lactams is reported that makes use of Pd0-catalyzed carbamoylation of C(sp3)?H bonds, and operates under stoichiometric carbon monoxide in a two-chamber reactor. This reaction is compatible with a range of primary, secondary and activated tertiary C?H bonds, in contrast to previous methods based on C(sp3)?H activation. In addition, the feasibility of an enantioselective version using a chiral phosphonite ligand is demonstrated. Finally, this method can be employed to synthesize valuable enantiopure free β-lactams and β-amino acids.

New Crystalline Hosts Based on Tartaric Acid. Synthesis, Inclusion Properties, and X-ray Structural Characterization of Interaction Modes with Alcohol Guests

A series of host molecules derived from tartaric acid have been synthesized in optically resolved and racemic forms.Apart from two endo hydroxyl functions and four bulky aromatic groups (TADDOL-type = α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanols),