cis-4-Nonene

Base Information

• Chemical Name: cis-4-Nonene
• CAS No.: 10405-84-2
• Molecular Formula: C9H18
• Molecular Weight: 126.242
• Hs Code.: 2901299090
• European Community (EC) Number: 678-275-7
• UNII: 9ZMZ6K438Y
• DSSTox Substance ID: DTXSID40874000
• Nikkaji Number: J87.945B
• Wikidata: Q27273428
• Mol file: 10405-84-2.mol

Synonyms:cis-4-Nonene;10405-84-2;(Z)-4-Nonene;4-Nonene, (Z)-;4-Nonene, (4Z)-;(Z)-non-4-ene;delta-cis-Nonene;(4Z)-4-Nonene;UNII-9ZMZ6K438Y;9ZMZ6K438Y;trans--4-Nonene;.DELTA.-CIS-NONENE;DTXSID40874000;KPADFPAILITQBG-CLFYSBASSA-N;MFCD00067487;(E)-4-C9H18;(Z)-4-C9H18;N0384;Q27273428

Chemical Property of cis-4-Nonene

Chemical Property:

• Vapor Pressure: 6.06mmHg at 25°C
• Refractive Index: 1.426
• Boiling Point: 143°C
• Flash Point: 27.2°C
• PSA: 0.00000
• Density: 0,73 g/cm3
• LogP: 3.53290
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 126.140850574
• Heavy Atom Count: 9
• Complexity: 62.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

cis-4-Nonene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC=CCCC
• Isomeric SMILES: CCCC/C=C\CCC
• Uses: cis-4-Nonene is used in preparation of Immobilized metal Alkylidene Imidazolidene Carbene Alkoxide catalysts and use thereof in olefin metathesis.

Technology Process of cis-4-Nonene

There total 13 articles about cis-4-Nonene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

pentylidenetriphenylphosphorane (29541-98-8,55317-64-1) → (Z)-4-nonene (10405-84-2,2198-23-4)

Guidance literature:

for 24h; Ambient temperature;

DOI:10.1021/ja00266a047

Reference yield:

(+/-)-1-propylhexyl 4-methylbenzenesulfonate (65950-00-7) → cis-3-nonene (20237-46-1) + (E)-3-nonene (20063-92-7) + (E)-non-4-ene (10405-85-3,2198-23-4) + (Z)-4-nonene (10405-84-2,2198-23-4)

Guidance literature:

With 18-crown-6 ether; potassium tert-butylate; In tert-butyl alcohol; at 25.4 ℃; Product distribution; Rate constant;

Reference yield:

(4R,5R)-4,5-Dibromo-nonane (85102-22-3,85102-23-4,90644-81-8) → (E)-non-4-ene (10405-85-3,2198-23-4) + (Z)-4-nonene (10405-84-2,2198-23-4)

Guidance literature:

With zinc; titanium tetrachloride; In tetrahydrofuran; at 0 ℃; for 3h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1055/s-1982-30049

upstream raw materials:

(+/-)-1-propylhexyl 4-methylbenzenesulfonate

4-(1-butyl-1(E)-pentenyl)morpholine

(4R,5R)-4,5-Dibromo-nonane

(4S,5R)-4,5-Dibromo-nonane

Downstream raw materials:

4-octene

(E)-non-4-ene

5-decene

cis-5-decene