5-Decene

Base Information

• Chemical Name: 5-Decene
• CAS No.: 19689-19-1
• Molecular Formula: C10H20
• Molecular Weight: 140.269
• European Community (EC) Number: 243-226-7
• DSSTox Substance ID: DTXSID00864063
• Wikidata: Q30118589
• Mol file: 19689-19-1.mol

Synonyms:5-Decene;Dec-5-ene;19689-19-1;EINECS 243-226-7;(5E)-5-Decene;DTXSID00864063;FT-0604946;FT-0694761;Q30118589

Chemical Property of 5-Decene

Chemical Property:

• Vapor Pressure: 2.08mmHg at 25°C
• Melting Point: -73°C
• Refractive Index: 1.4331
• Boiling Point: 169°Cat760mmHg
• Flash Point: 45.5°C
• PSA: 0.00000
• Density: 0.749g/cm³
• LogP: 3.92300
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 140.156500638
• Heavy Atom Count: 10
• Complexity: 62.1

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Unsaturated
• Canonical SMILES: CCCCC=CCCCC

Technology Process of 5-Decene

There total 59 articles about 5-Decene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-Decene (872-05-9,17438-89-0,25189-70-2) → 5-decene (19689-19-1) + 4-decene (19689-18-0) + trans-3-decene (19150-21-1) + Decan-2-one (693-54-9) + 2-decene (20063-97-2,20348-51-0,6816-17-7)

Guidance literature:

With oxygen; 2,6-di-O-methyl-β-cyclodextrin; palladium(II) sulfate; H₉PV₆Mo₆O₄₀; copper(II) sulfate; In water; at 80 ℃; for 6h; under 750.06 Torr; Mechanism; Product distribution; influence of composition of catalytic mixture on selectivity of reaction;

Reference yield: 77.0%

1-hexene (592-41-6,25067-06-5) → ethene (74-85-1) + 5-decene (19689-19-1)

Guidance literature:

silica gel; methyltrioxorhenium(VII); In dichloromethane; for 0.5h; Heating; olefin metathesis; further alkenes;

Reference yield: 26.0%

C12H24B(1-)*Li(1+) (121826-81-1) → 2-Methyl-2-heptanol (625-25-2) + hept-2-ene (592-77-8) + 5-decene (19689-19-1) + hex-1-yne (693-02-7)

Guidance literature:

Yield given. Multistep reaction. Further byproducts given;

DOI:10.1016/S0040-4039(00)80450-5

upstream raw materials:

(E)-1,4-dibromobutene

n-propylmagnesium bromide

propyl bromide

buta-1,3-diene

Downstream raw materials:

1-hexene

diethyl 19-octadecene-1,18-dioate

myristoleic acid ethyl ester

Ethyl-tetradec-9-enoate

Refernces

• 1、 Shcheglova,Kolesnik,Ashirov,Krasnokutskaya. "N-chelate ruthenium carbene complexes in olefin metathesis and isomerization". . p. 907 - 909. Retrieved 2015.
• 2、 Bykov,Belyaev,Butenko,Finkel'Shtein. "New active heterogeneous olefin metathesis catalyst based on molybdenum oxotetrachloride". . p. 615 - 615. Retrieved 2010.
• 3、 Tamao et al.. "". . p. 5603. Retrieved 1975.
• 4、 Bykov,Belyaev,Butenko,Finkel'shtein. "Olefin metathesis catalyst systems based on molybdenum halides and organosilicon compounds". . p. 121 - 124. Retrieved 2016.
• 5、 De Jesus Silva, Jordan,Pucino, Margherita,Zhai, Feng,Mance, Deni,Berkson, Zachariah J.,Nater, Darryl F.,Hoveyda, Amir H.,Copéret, Christophe,Schrock, Richard R.. "Boosting the Metathesis Activity of Molybdenum Oxo Alkylidenes by Tuning the Anionic Ligand σ Donation". supporting information. p. 6875 - 6880. Retrieved 2021/02/06.
• 6、 Diver, Steven T.,Zhang, Yutong. "A Macrocyclic Ruthenium Carbene for Size-Selective Alkene Metathesis". supporting information. . Retrieved 2020/02/22.