(-)-Dihydromyrcene

Base Information

• Chemical Name: (-)-Dihydromyrcene
• CAS No.: 10281-56-8
• Molecular Formula: C10H18
• Molecular Weight: 138.253
• Hs Code.: 2901299090
• European Community (EC) Number: 629-287-6
• UNII: 18B648YA2C
• DSSTox Substance ID: DTXSID0058726
• Nikkaji Number: J63.955I
• Wikidata: Q27251992
• Mol file: 10281-56-8.mol

Synonyms:beta-citronellene;citronellene

Chemical Property of (-)-Dihydromyrcene

Chemical Property:

• Vapor Pressure: 2.186mmHg at 25°C
• Refractive Index: n20/D 1.439
• Boiling Point: ~155 °C(lit.)
• Flash Point: 38 °C
• PSA: 0.00000
• Density: 0.761 g/mL at 20 °C(lit.)
• LogP: 3.55490
• Storage Temp.: 2-8°C
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 138.140850574
• Heavy Atom Count: 10
• Complexity: 116

Purity/Quality:

98%,99%, ^*data from raw suppliers

(-)-BETA-CITRONELLENE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 10
• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(CCC=C(C)C)C=C
• Isomeric SMILES: C[C@H](CCC=C(C)C)C=C

Technology Process of (-)-Dihydromyrcene

There total 13 articles about (-)-Dihydromyrcene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

→ (R)-3,7-dimethyl-1,6-octadiene (10281-56-8)

Guidance literature:

Reference yield: 76.0%

O-(3,7-dimethyloct-6-en-1-yl) S-methyl carbonodithioate → (R)-3,7-dimethyl-1,6-octadiene (10281-56-8)

Guidance literature:

at 280 ℃; Further stages;

DOI:10.3390/molecules26185540

Reference yield:

(Z)-3,7-dimethylocta-2,6-dien-1-yl methyl carbonate (85217-73-8) → (S)-(+)-dihydromyrcene (2436-90-0) + (R)-3,7-dimethyl-1,6-octadiene (10281-56-8)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; formic acid; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; (R)-(+)-3-diphenylphosphino-3'-methoxy-4,4'-biphenanthryl; In 1,4-dioxane; at 20 ℃; for 15h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/ja00081a051

upstream raw materials:

(1S)-(-)-cis-pinane

(3R)-citronellol

(Z)-3,7-dimethylocta-2,6-dien-1-yl methyl carbonate

geranyl methyl carbonate

Downstream raw materials:

(-)-3,3-Dimethylcyclohexylacetat

3-methyl-1-cyclopentene

C₂₀H₂₄N₂O₂

(R)-(-)-2,6-dimethyl-5-heptenal