endo-6'-Carbomethoxyspiro<1,3-dioxolane-2,2'-bicyclo<2.2.1>heptane>

Base Information

Chemical Name:endo-6'-Carbomethoxyspiro<1,3-dioxolane-2,2'-bicyclo<2.2.1>heptane>
CAS No.:70600-43-0
Molecular Formula:C₁₁H₁₆O₄
Molecular Weight:212.246
Hs Code.:

Synonyms:endo-6'-Carbomethoxyspiro<1,3-dioxolane-2,2'-bicyclo<2.2.1>heptane>

Suppliers and Price of endo-6'-Carbomethoxyspiro<1,3-dioxolane-2,2'-bicyclo<2.2.1>heptane>

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of endo-6'-Carbomethoxyspiro<1,3-dioxolane-2,2'-bicyclo<2.2.1>heptane>

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Technology Process of endo-6'-Carbomethoxyspiro<1,3-dioxolane-2,2'-bicyclo<2.2.1>heptane>

There total 1 articles about endo-6'-Carbomethoxyspiro<1,3-dioxolane-2,2'-bicyclo<2.2.1>heptane> which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 120-74-1,934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7
5-carboxybicyclo<2.2.1>hept-2-ene

: 70600-43-0
endo-6'-Carbomethoxyspiro<1,3-dioxolane-2,2'-bicyclo<2.2.1>heptane>

Guidance literature:: Multi-step reaction with 4 steps

1: 57 percent / aq. NaHCO₃; Br₂ / 0.5 h / 0 °C

2: 64 percent / NaOH / H₂O / 1 h / 25 °C

3: 94 percent / methanol / 2 h

4: 85 percent / p-TsOH / benzene / 6 h / Heating

With sodium hydroxide; bromine; sodium hydrogencarbonate; toluene-4-sulfonic acid; In methanol; water; benzene; 1: Cyclization / 2: Ring cleavage / 3: Methylation / 4: Cyclization;
DOI:10.1016/S0968-0896(00)00094-8

Reference yield:

: 70600-43-0
endo-6'-Carbomethoxyspiro<1,3-dioxolane-2,2'-bicyclo<2.2.1>heptane>

: 81523-34-4
6-endo-(acetoxymethyl)-2-norbornanone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) lithium aluminum hydride, 2.) hydrochloric acid / 1.) ether, 4 h, 2.) room temperature, 3 h

2: 84 percent / pyridine / Ambient temperature

With hydrogenchloride; lithium aluminium tetrahydride; In pyridine;
DOI:10.1021/ja00378a033

Reference yield:

: 70600-43-0
endo-6'-Carbomethoxyspiro<1,3-dioxolane-2,2'-bicyclo<2.2.1>heptane>

: 81523-31-1
6-endo-(Hydroxymethyl)bicyclo<2.2.1>heptan-2-one

Guidance literature:: With hydrogenchloride; lithium aluminium tetrahydride; Yield given. Multistep reaction; 1.) ether, 4 h, 2.) room temperature, 3 h;
DOI:10.1021/ja00378a033