(S)-N-{4-(tert-butyldimethylsilanyloxy)-2-[2-(2,2-dimethyl-5-oxo[1,3]dioxolan-4-yl)acetyl]phenyl}-4-(pyren-1-yl)butyramide

Base Information

Chemical Name:(S)-N-{4-(tert-butyldimethylsilanyloxy)-2-[2-(2,2-dimethyl-5-oxo[1,3]dioxolan-4-yl)acetyl]phenyl}-4-(pyren-1-yl)butyramide
CAS No.:929006-15-5
Molecular Formula:C₃₉H₄₃NO₆Si
Molecular Weight:649.859
Hs Code.:

Synonyms:(S)-N-{4-(tert-butyldimethylsilanyloxy)-2-[2-(2,2-dimethyl-5-oxo[1,3]dioxolan-4-yl)acetyl]phenyl}-4-(pyren-1-yl)butyramide

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Chemical Property of (S)-N-{4-(tert-butyldimethylsilanyloxy)-2-[2-(2,2-dimethyl-5-oxo[1,3]dioxolan-4-yl)acetyl]phenyl}-4-(pyren-1-yl)butyramide

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Technology Process of (S)-N-{4-(tert-butyldimethylsilanyloxy)-2-[2-(2,2-dimethyl-5-oxo[1,3]dioxolan-4-yl)acetyl]phenyl}-4-(pyren-1-yl)butyramide

There total 3 articles about (S)-N-{4-(tert-butyldimethylsilanyloxy)-2-[2-(2,2-dimethyl-5-oxo[1,3]dioxolan-4-yl)acetyl]phenyl}-4-(pyren-1-yl)butyramide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 929006-14-4
(S)-{2-[2-amino-5-(tert-butyldimethylsilanyloxy)phenyl]-2-oxoethyl}-2,2-dimethyl[1,3]dioxolan-4-one

: 63549-37-1
4-(pyren-1-yl)butyryl chloride

: 929006-15-5
(S)-N-{4-(tert-butyldimethylsilanyloxy)-2-[2-(2,2-dimethyl-5-oxo[1,3]dioxolan-4-yl)acetyl]phenyl}-4-(pyren-1-yl)butyramide

Guidance literature:: With pyridine; In dichloromethane; at 20 ℃; for 7h;
DOI:10.1016/j.bmc.2006.12.021

Reference yield:

: 229032-21-7
(S)-{4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(2,2-dimethyl-5-oxo-[1,3]dioxolan-4-yl)-acetyl]-phenyl}-carbamic acid tert-butyl ester

: 929006-15-5
(S)-N-{4-(tert-butyldimethylsilanyloxy)-2-[2-(2,2-dimethyl-5-oxo[1,3]dioxolan-4-yl)acetyl]phenyl}-4-(pyren-1-yl)butyramide

Guidance literature:: Multi-step reaction with 2 steps

1: 67 percent / TFA; anisole / acetone / 9 h / 20 °C

2: 72 percent / pyridine / CH₂Cl₂ / 7 h / 20 °C

With pyridine; methoxybenzene; trifluoroacetic acid; In dichloromethane; acetone;
DOI:10.1016/j.bmc.2006.12.021

Reference yield:

: 3443-45-6
1-pyrenebutyric acid

: 929006-15-5
(S)-N-{4-(tert-butyldimethylsilanyloxy)-2-[2-(2,2-dimethyl-5-oxo[1,3]dioxolan-4-yl)acetyl]phenyl}-4-(pyren-1-yl)butyramide

Guidance literature:: Multi-step reaction with 2 steps

1: oxalyl chloride / CH₂Cl₂; dimethylformamide / 0.75 h / 20 °C

2: 72 percent / pyridine / CH₂Cl₂ / 7 h / 20 °C

With pyridine; oxalyl dichloride; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2006.12.021