1-PYRENEBUTYRYL CHLORIDE

Base Information

• Chemical Name: 1-PYRENEBUTYRYL CHLORIDE
• CAS No.: 63549-37-1
• Molecular Formula: C20H15ClO
• Molecular Weight: 306.791
• Hs Code.: 2916399090
• DSSTox Substance ID: DTXSID50392604
• Nikkaji Number: J647.689I
• Wikidata: Q82190961
• Mol file: 63549-37-1.mol

Synonyms:4-pyren-1-yl-butyroyl chloride;1-Pyrenebutanoyl chloride;1-Pyrenebutyryl Chloride;1-pyrenebutyric chloride;1-pyrenebutyric acid chloride;pyrene-1-butyric acid chloride;4-pyrenylbutanoyl chloride;

Chemical Property of 1-PYRENEBUTYRYL CHLORIDE

Chemical Property:

• Melting Point: 80-81oC
• Boiling Point: 488.1±24.0 °C(Predicted)
• PSA: 17.07000
• Density: 1.298±0.06 g/cm3(Predicted)
• LogP: 5.67210
• Storage Temp.: Hygroscopic, Refrigerator, Under Inert Atmosphere
• XLogP3: 6.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 306.0811428
• Heavy Atom Count: 22
• Complexity: 420

Purity/Quality:

98%Min ^*data from raw suppliers

1-PyrenebutyrylChloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C3C(=C1)C=CC4=C(C=CC(=C43)C=C2)CCCC(=O)Cl
• Uses: 1-Pyrenebutyryl Chloride (cas# 63549-37-1) is a compound useful in organic synthesis.

Technology Process of 1-PYRENEBUTYRYL CHLORIDE

There total 1 articles about 1-PYRENEBUTYRYL CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-pyrenebutyric acid (3443-45-6) → 4-(pyren-1-yl)butyryl chloride (63549-37-1)

Guidance literature:

With sulfuryl dichloride; In benzene;

DOI:10.1016/j.tet.2006.09.042

Reference yield: 83.0%

4-(pyren-1-yl)butyryl chloride (63549-37-1) + 2-aminoacetophenone (551-93-9) → C28H23NO2

Guidance literature:

With pyridine; In dichloromethane; at 20 ℃;

DOI:10.1016/j.bmc.2006.12.021

Reference yield: 78.0%

4-(pyren-1-yl)butyryl chloride (63549-37-1) + (L)-phenylalanine ethyl ester hydrochloride (3182-93-2) → N-[1-oxo-4-(1-pyrenyl)butyl]-phenylalanine ethyl ester

Guidance literature:

With triethylamine; In chloroform; at 20 ℃; for 4h;

DOI:10.1039/c7cc06915d

upstream raw materials:

1-pyrenebutyric acid

Downstream raw materials:

cholesteryl 1-pyrenebutyrate

N-(6-pentanamido-2-pyridyl)-N'-<6-<4-(1-pyrenyl)butanamido>-2-pyridyl>isophthalamide

9,10-dihydrobenzo[a]pyren-(8H)-none

4-(1-pyrenyl)butyric amide

Refernces

• 1、 Hou, Chen,Xiong, Yijia,Fu, Na,Jacquot, Caitlin C.,Squier, Thomas C.,Cao, Haishi. "Turn-on ratiometric fluorescent sensor for Pb2+ detection". . p. 2692 - 2696. Retrieved 2011.
• 2、 Chebotareva, Natalia,Bomans, Paul H. H.,Frederik, Peter M.,Sommerdijk, Nico A. J. M.,Sijbesma, Rint P.. "Morphological control and molecular recognition by bis-urea hydrogen bonding in micelles of amphiphilic tri-block copolymers". . p. 4967 - 4969. Retrieved 2005.
• 3、 Bhat, Shreedhar,Valkonen, Arto,Koivukorpi, Juha,Ambika, Anupama,Kolehmainen, Erkki,Maitra, Uday,Rissanen, Kari. "Pyrene appended bile acid conjugates: Synthesis and a structure-Gelation property study". . p. 379 - 391. Retrieved 2011.
• 4、 Hayashita, Takashi,Qing, Dai,Minagawa, Masakazu,Lee, Jong Chan,Ku, Chang Hoe,Teramae, Norio. "Highly selective recognition of lead ion in water by a podand fluoroionophore/γ-cyclodextrin complex sensor". . p. 2160 - 2161. Retrieved 2003.
• 5、 Gomez, Fernando J.,Chen, Robert J.,Wang, Dunwei,Waymouth, Robert M.,Dai, Hongjie. "Ring opening metathesis polymerization on non-covalently functionalized single-walled carbon nanotubes". . p. 190 - 191. Retrieved 2003.
• 6、 Lou, Jianfeng,Hatton, T. Alan,Laibinis, Paul E.. "Fluorescent probes for monitoring temperature in organic solvents". . p. 1262 - 1264. Retrieved 1997.
• 7、 Fu,Xie,Tan,Ren,Zhao,Webley,Qiao. "The use of reduced copper metal-organic frameworks to facilitate CuAAC click chemistry". . p. 12226 - 12229. Retrieved 2016.
• 8、 Abraham, Shibu,Atvars, Teresa D. Z.,Weiss, Richard G.. "Effects of temperature and Alkyl groups of poly(Alkyl methacrylate)s on inter- and intramolecular interactions of excited singlet states of pyrenyl guest molecules". . p. 12221 - 12233. Retrieved 2010.
• 9、 Zhu, Weihua,Zhang, Honglin,Liu, Siqi,Wang, Aijian,Liang, Xu. "Efficient nonlinear-optical behaviors of chiral-amide-bonded porphyrin noncovalent functionalized MWCNTs by terminated pyrene units". . p. 14890 - 14895. Retrieved 2020/10/02.
• 10、 -. "Novel pyrene compound, preparation method thereof, carbon nanotubes surface modified with the same, carbon nanotube-bucky paper comprising the same and preparationa method thereof". Paragraph 0084; 0085. . Retrieved 2018/05/29.