Ethyl cyclooctylideneacetate

Base Information

Chemical Name:Ethyl cyclooctylideneacetate
CAS No.:1903-24-8
Molecular Formula:C₁₂H₂₀O₂
Molecular Weight:196.29
Hs Code.:2916209090
DSSTox Substance ID:DTXSID30554046
Mol file:1903-24-8.mol

Synonyms:Ethyl cyclooctylideneacetate;1903-24-8;ETHYL 2-CYCLOOCTYLIDENEACETATE;CYCLOOCTYLIDENEACETIC ACID ETHYL ESTER;ethyl 2-cyclooctanylideneacetate;SCHEMBL4687838;DTXSID30554046;FMPNNLCEQAFVEF-UHFFFAOYSA-N;AKOS006287902;EN300-1455290

Suppliers and Price of Ethyl cyclooctylideneacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
CYCLOOCTYLIDENEACETIC ACID ETHYL ESTER 95.00%
5MG
$ 503.29

Total 8 raw suppliers

Chemical Property of Ethyl cyclooctylideneacetate

Chemical Property:

Vapor Pressure:0.00471mmHg at 25°C
Refractive Index:1.513
Boiling Point:276.8°Cat760mmHg
Flash Point:136.2°C
PSA：26.30000
Density:1.003g/cm³
LogP:3.22020
XLogP3:3.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:196.146329876
Heavy Atom Count:14
Complexity:196

Purity/Quality:

98%,99%, ^*data from raw suppliers

CYCLOOCTYLIDENEACETIC ACID ETHYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C=C1CCCCCCC1

Technology Process of Ethyl cyclooctylideneacetate

There total 2 articles about Ethyl cyclooctylideneacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 502-49-8
cycloactanone

: 867-13-0
diethoxyphosphoryl-acetic acid ethyl ester

: 1903-24-8
ethyl cyclooctylideneacetate

Guidance literature:: diethoxyphosphoryl-acetic acid ethyl ester; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.5h;

cycloactanone; In tetrahydrofuran; at 20 ℃; for 8h;

Reference yield:

: 5095-70-5
1-<(ethoxycarbonyl)methyl>cyclooctanol

: 1903-24-8
ethyl cyclooctylideneacetate

: 105540-55-4
ethyl cycloocten-1-ylacetate

Guidance literature:: With toluene-4-sulfonic acid; In benzene; for 20h; Heating;
DOI:10.1021/jo00239a045

Reference yield:

: 1903-24-8
ethyl cyclooctylideneacetate

: 146449-15-2
7-Hydroxy-2-[2-(4-methyl-cyclohexyl)-ethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one

Guidance literature:: Multi-step reaction with 6 steps

1: H₂ / 5percent Pd/C / ethanol / 760 Torr

2: 94.5 percent / LiAlH₄ / tetrahydrofuran

3: 64.2 percent / PBr₃ / diethyl ether; diethyl ether / 16 h / Ambient temperature

4: dimethylsulfoxide

5: 16.7 percent / CF₃COOH

6: 35 percent / heptane / 2 h / 140 - 150 °C

With lithium aluminium tetrahydride; hydrogen; phosphorus tribromide; trifluoroacetic acid; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; ethanol; n-heptane; dimethyl sulfoxide;
DOI:10.1248/cpb.40.2391