4-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)butyl 3-chloro-2-(hex-5-enyl)-4,6-dihydroxybenzoate

Base Information

Chemical Name:4-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)butyl 3-chloro-2-(hex-5-enyl)-4,6-dihydroxybenzoate
CAS No.:913623-04-8
Molecular Formula:C₂₈H₃₆ClNO₁₁
Molecular Weight:598.047
Hs Code.:

Synonyms:4-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)butyl 3-chloro-2-(hex-5-enyl)-4,6-dihydroxybenzoate

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Chemical Property of 4-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)butyl 3-chloro-2-(hex-5-enyl)-4,6-dihydroxybenzoate

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Technology Process of 4-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)butyl 3-chloro-2-(hex-5-enyl)-4,6-dihydroxybenzoate

There total 8 articles about 4-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)butyl 3-chloro-2-(hex-5-enyl)-4,6-dihydroxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 913622-79-4
3-chloro-2-(5-hexenyl)-4,6-dihydroxybenzoic acid

: 913622-70-5
4-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)butan-1-ol

: 913623-04-8
4-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)butyl 3-chloro-2-(hex-5-enyl)-4,6-dihydroxybenzoate

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 0 - 20 ℃; for 10h;
DOI:10.1021/jo061054f

Reference yield:

: 913622-69-2
4-(2-methoxy-3,6-bis(methoxymethoxy)phenyl)butan-1-ol

: 913623-04-8
4-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)butyl 3-chloro-2-(hex-5-enyl)-4,6-dihydroxybenzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: NH₄NO₃; (CF₃CO)2O / tetrahydrofuran / 1 h / 20 °C

1.2: 85 percent / LiOH / tetrahydrofuran; methanol; H₂O / 0.17 h

2.1: 84 percent / PPh₃; diisopropyl azodicarboxylate / tetrahydrofuran / 10 h / 0 - 20 °C

With ammonium nitrate; di-isopropyl azodicarboxylate; triphenylphosphine; trifluoroacetic anhydride; In tetrahydrofuran; 2.1: Mitsunobu esterification;
DOI:10.1021/jo061054f

Reference yield:

: 811788-11-1
methyl 2,4-bis(tert-butyldimethylsilanyloxy)-3-chloro-6-methylbenzoate

: 913623-04-8
4-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)butyl 3-chloro-2-(hex-5-enyl)-4,6-dihydroxybenzoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: 82 percent / LDA / tetrahydrofuran; heptane / -40 °C

2.1: LiOH / tetrahydrofuran; methanol; H₂O / 1 h / 20 °C

2.2: 76 percent / HMPA; nPrSLi / 2.5 h / 20 °C

3.1: 84 percent / PPh₃; diisopropyl azodicarboxylate / tetrahydrofuran / 10 h / 0 - 20 °C

With lithium hydroxide; di-isopropyl azodicarboxylate; triphenylphosphine; lithium diisopropyl amide; In tetrahydrofuran; methanol; n-heptane; water; 3.1: Mitsunobu esterification;
DOI:10.1021/jo061054f