(3S,5R,6S)-5-hydroxy-1-((4-methoxybenzyl)oxy)-6-methylnon-8-en-3-yl 2-allyl-6-hydroxybenzoate

Base Information

Chemical Name:(3S,5R,6S)-5-hydroxy-1-((4-methoxybenzyl)oxy)-6-methylnon-8-en-3-yl 2-allyl-6-hydroxybenzoate
CAS No.:1298015-37-8
Molecular Formula:C₂₈H₃₆O₆
Molecular Weight:468.59
Hs Code.:

Synonyms:(3S,5R,6S)-5-hydroxy-1-((4-methoxybenzyl)oxy)-6-methylnon-8-en-3-yl 2-allyl-6-hydroxybenzoate

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Chemical Property of (3S,5R,6S)-5-hydroxy-1-((4-methoxybenzyl)oxy)-6-methylnon-8-en-3-yl 2-allyl-6-hydroxybenzoate

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Technology Process of (3S,5R,6S)-5-hydroxy-1-((4-methoxybenzyl)oxy)-6-methylnon-8-en-3-yl 2-allyl-6-hydroxybenzoate

There total 1 articles about (3S,5R,6S)-5-hydroxy-1-((4-methoxybenzyl)oxy)-6-methylnon-8-en-3-yl 2-allyl-6-hydroxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1298015-27-6
(3S,5R,6S)-1-((4-methoxybenzyl)oxy)-6-methylnon-8-ene-3,5-diol

: 204846-40-2
2,2-dimethyl-5-(2-propenyl)-4H-1,3-benzodioxin-4-one

: 1298015-37-8
(3S,5R,6S)-5-hydroxy-1-((4-methoxybenzyl)oxy)-6-methylnon-8-en-3-yl 2-allyl-6-hydroxybenzoate

: 1298015-38-9
(4S,5R,7S)-7-hydroxy-9-((4-methoxybenzyl)oxy)-4-methylnon-1-en-5-yl 2-allyl-6-hydroxybenzoate

Guidance literature:: (3S,5R,6S)-1-((4-methoxybenzyl)oxy)-6-methylnon-8-ene-3,5-diol; With sodium hexamethyldisilazane; In tetrahydrofuran; at -20 ℃; for 0.25h; Inert atmosphere;

2,2-dimethyl-5-(2-propenyl)-4H-1,3-benzodioxin-4-one; In tetrahydrofuran; at -20 - 0 ℃; regioselective reaction; Inert atmosphere;
DOI:10.1021/jo200337v

Reference yield: 86.0%

: 1298015-37-8
(3S,5R,6S)-5-hydroxy-1-((4-methoxybenzyl)oxy)-6-methylnon-8-en-3-yl 2-allyl-6-hydroxybenzoate

: 107-30-2
chloromethyl methyl ether

: 420794-28-1
(3S,5R,6S)-1-((4-methoxybenzyl)oxy)-5-(methoxymethoxy)-6-methylnon-8-en-3-yl 2-allyl-6-(methoxymethoxy)benzoate

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In 1,2-dichloro-ethane; at 90 ℃; Inert atmosphere;
DOI:10.1021/jo200337v

Reference yield:

: 1298015-37-8
(3S,5R,6S)-5-hydroxy-1-((4-methoxybenzyl)oxy)-6-methylnon-8-en-3-yl 2-allyl-6-hydroxybenzoate

: (3S,5R,6S,Z)-3-(2-((4-methoxybenzyl)oxy)-ethyl)-5,14-bis(methoxymethoxy)-6-methyl-3,4,5,6,7,10-hexahydro-1H-benzo[c][1]oxacyclododecin-1-one

: (3S,5R,6S,E)-3-(2-((4-methoxybenzyl)oxy)-ethyl)-5,14-bis(methoxymethoxy)-6-methyl-3,4,5,6,7,10-hexahydro-1H-benzo[c][1]oxacyclododecin-1-one

Guidance literature:: Multi-step reaction with 2 steps

1: N-ethyl-N,N-diisopropylamine / 1,2-dichloro-ethane / 90 °C / Inert atmosphere

2: Grubbs catalyst first generation / dichloromethane / 1 h / 40 °C / Inert atmosphere

With Grubbs catalyst first generation; N-ethyl-N,N-diisopropylamine; In dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/jo200337v