(3S,5R,6S)-1-((4-methoxybenzyl)oxy)-5-(methoxymethoxy)-6-methylnon-8-en-3-yl 2-allyl-6-(methoxymethoxy)benzoate

Base Information

Chemical Name:(3S,5R,6S)-1-((4-methoxybenzyl)oxy)-5-(methoxymethoxy)-6-methylnon-8-en-3-yl 2-allyl-6-(methoxymethoxy)benzoate
CAS No.:420794-28-1
Molecular Formula:C₃₂H₄₄O₈
Molecular Weight:556.697
Hs Code.:

Synonyms:(3S,5R,6S)-1-((4-methoxybenzyl)oxy)-5-(methoxymethoxy)-6-methylnon-8-en-3-yl 2-allyl-6-(methoxymethoxy)benzoate

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Chemical Property of (3S,5R,6S)-1-((4-methoxybenzyl)oxy)-5-(methoxymethoxy)-6-methylnon-8-en-3-yl 2-allyl-6-(methoxymethoxy)benzoate

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Technology Process of (3S,5R,6S)-1-((4-methoxybenzyl)oxy)-5-(methoxymethoxy)-6-methylnon-8-en-3-yl 2-allyl-6-(methoxymethoxy)benzoate

There total 16 articles about (3S,5R,6S)-1-((4-methoxybenzyl)oxy)-5-(methoxymethoxy)-6-methylnon-8-en-3-yl 2-allyl-6-(methoxymethoxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1298015-37-8
(3S,5R,6S)-5-hydroxy-1-((4-methoxybenzyl)oxy)-6-methylnon-8-en-3-yl 2-allyl-6-hydroxybenzoate

: 107-30-2
chloromethyl methyl ether

: 420794-28-1
(3S,5R,6S)-1-((4-methoxybenzyl)oxy)-5-(methoxymethoxy)-6-methylnon-8-en-3-yl 2-allyl-6-(methoxymethoxy)benzoate

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In 1,2-dichloro-ethane; at 90 ℃; Inert atmosphere;
DOI:10.1021/jo200337v

Reference yield:

: 204846-40-2
2,2-dimethyl-5-(2-propenyl)-4H-1,3-benzodioxin-4-one

: 420794-28-1
(3S,5R,6S)-1-((4-methoxybenzyl)oxy)-5-(methoxymethoxy)-6-methylnon-8-en-3-yl 2-allyl-6-(methoxymethoxy)benzoate

Guidance literature:: Multi-step reaction with 4 steps

1.1: EtMgBr / tetrahydrofuran / 0.25 h / 20 °C

1.2: 90 percent / tetrahydrofuran / 7.5 h / 20 - 60 °C

2.1: 90 percent / NaI; i-Pr₂EtN / 1,2-dimethoxy-ethane; dimethylformamide / 17 h / 20 - 55 °C

3.1: Pd(PPh₃)4; morpholine / tetrahydrofuran / 1 h / 20 °C

4.1: DEAD; PPh₃ / diethyl ether / 4 h / Heating

With morpholine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; ethylmagnesium bromide; N-ethyl-N,N-diisopropylamine; triphenylphosphine; sodium iodide; diethylazodicarboxylate; In tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether; N,N-dimethyl-formamide; 4.1: Mitsunobu esterification;
DOI:10.1021/ja0177713

Reference yield:

: 398478-25-6
2-methoxymethoxy-6-(prop-2-enyl)benzoic acid allyl ester

: 420794-28-1
(3S,5R,6S)-1-((4-methoxybenzyl)oxy)-5-(methoxymethoxy)-6-methylnon-8-en-3-yl 2-allyl-6-(methoxymethoxy)benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: Pd(PPh₃)4; morpholine / tetrahydrofuran / 1 h / 20 °C

2: DEAD; PPh₃ / diethyl ether / 4 h / Heating

With morpholine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; diethyl ether; 2: Mitsunobu esterification;
DOI:10.1021/ja0177713