Ni(C₆H₅PCl₂)4

Base Information

• Chemical Name: Ni(C₆H₅PCl₂)4
• CAS No.: 15675-30-6
• Molecular Formula: C₂₄H₂₀Cl₈NiP₄
• Molecular Weight: 774.632
• Mol file: 15675-30-6.mol

Synonyms:Ni(C₆H₅PCl₂)4

Chemical Property of Ni(C₆H₅PCl₂)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of Ni(C₆H₅PCl₂)4

There total 2 articles about Ni(C₆H₅PCl₂)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dichlorophenylphosphine (644-97-3) + tetracarbonyl nickel (13463-39-3,71564-36-8) → Ni(C6H5PCl2)4 (15675-30-6)

Guidance literature:

In neat (no solvent); heating;; pptn.;;

Reference yield:

tetrakis(methyldichlorophosphine)nickel(0) (76404-15-4) + Dichlorophenylphosphine (644-97-3) → Ni(C6H5PCl2)4 (15675-30-6)

Guidance literature:

In further solvent(s); byproducts: PCL2CH3; heating soln. of (Ni(PCl2CH3)4) in PCl2C6H5 at 35 Torr for 3 h to 70-80°C (stirring);; removal of excess PCl2C6H5 by vac. distn., residue washed with n-pentane, recrystn. from ether;;

DOI:10.1021/ja01571a020

Reference yield:

zinc(II) fluoride + Ni(C6H5PCl2)4 (15675-30-6) → {Ni(PF2C6H5)4} (13987-00-3)

Guidance literature:

In benzene; refluxing ZnF2 and soln. of (Ni(PCl2C6H5)4) in benzene for 4 h in N2-atmosphere, stirring for 10 h at ambient temp.;; pumping off volatile components at 1 torr, dissolving residue in benzene, filtering under N2, concg. in vac., dissolving in ether, treating withactivated carbon, evapg. ether, addn. of petroleum ether, cooling with ice, recrystn., drying in vac.;;

upstream raw materials:

Dichlorophenylphosphine

tetracarbonyl nickel

tetrakis(methyldichlorophosphine)nickel⁽⁰⁾

Downstream raw materials:

{Ni(PF₂C₆H₅)4}