(((1S,2R,3R,5R)-2-((4-chlorophen)ethyl)-1,4,4-trimethyl-8-oxabicyclo[3.2.1]octan-3-yl)oxy)triisopropylsilane

Base Information

Chemical Name:(((1S,2R,3R,5R)-2-((4-chlorophen)ethyl)-1,4,4-trimethyl-8-oxabicyclo[3.2.1]octan-3-yl)oxy)triisopropylsilane
CAS No.:1402735-96-9
Molecular Formula:C₂₇H₄₅ClO₂Si
Molecular Weight:465.192
Hs Code.:

Synonyms:(((1S,2R,3R,5R)-2-((4-chlorophen)ethyl)-1,4,4-trimethyl-8-oxabicyclo[3.2.1]octan-3-yl)oxy)triisopropylsilane

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Chemical Property of (((1S,2R,3R,5R)-2-((4-chlorophen)ethyl)-1,4,4-trimethyl-8-oxabicyclo[3.2.1]octan-3-yl)oxy)triisopropylsilane

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Technology Process of (((1S,2R,3R,5R)-2-((4-chlorophen)ethyl)-1,4,4-trimethyl-8-oxabicyclo[3.2.1]octan-3-yl)oxy)triisopropylsilane

There total 2 articles about (((1S,2R,3R,5R)-2-((4-chlorophen)ethyl)-1,4,4-trimethyl-8-oxabicyclo[3.2.1]octan-3-yl)oxy)triisopropylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 1402736-17-7
(4R,5R)-2-((E)-6-(4-chlorophenyl)-3-methylhex-3-en-1-yl)-4,5-dimethyl-1,3-dioxolane

: triisopropyl((2-methylprop-1-en-1-yl)oxy)silane

: 1402735-96-9
(((1S,2R,3R,5R)-2-((4-chlorophen)ethyl)-1,4,4-trimethyl-8-oxabicyclo[3.2.1]octan-3-yl)oxy)triisopropylsilane

Guidance literature:: With titanium tetrachloride; In dichloromethane; at -78 ℃; for 10h; optical yield given as %ee; enantioselective reaction; Molecular sieve;
DOI:10.1002/anie.201202699

Reference yield:

: 1402736-34-8
C₁₈H₂₇ClO₂

: 1402735-96-9
(((1S,2R,3R,5R)-2-((4-chlorophen)ethyl)-1,4,4-trimethyl-8-oxabicyclo[3.2.1]octan-3-yl)oxy)triisopropylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: toluene-4-sulfonic acid / dichloromethane / 5 h / 20 °C

2: titanium tetrachloride / dichloromethane / 10 h / -78 °C / Molecular sieve

With titanium tetrachloride; toluene-4-sulfonic acid; In dichloromethane;
DOI:10.1002/anie.201202699

Reference yield: 88.0%

: 1402735-96-9
(((1S,2R,3R,5R)-2-((4-chlorophen)ethyl)-1,4,4-trimethyl-8-oxabicyclo[3.2.1]octan-3-yl)oxy)triisopropylsilane

: 1402735-93-6
(1S,2R,3R,5R)-2-((4-chlorophen)ethyl)-1,4,4-trimethyl-8-oxabicyclo[3.2.1]octan-3-ol

Guidance literature:: (((1S,2R,3R,5R)-2-((4-chlorophen)ethyl)-1,4,4-trimethyl-8-oxabicyclo[3.2.1]octan-3-yl)oxy)triisopropylsilane; With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 - 20 ℃; for 12h;

With ammonium chloride; In tetrahydrofuran;
DOI:10.1002/anie.201202699