Acetic acid (1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5-hydroxy-6-nitro-octyl ester

Base Information

Chemical Name:Acetic acid (1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5-hydroxy-6-nitro-octyl ester
CAS No.:127263-08-5
Molecular Formula:C₃₉H₄₅NO₉
Molecular Weight:671.788
Hs Code.:

Synonyms:Acetic acid (1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5-hydroxy-6-nitro-octyl ester

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Chemical Property of Acetic acid (1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5-hydroxy-6-nitro-octyl ester

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Technology Process of Acetic acid (1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5-hydroxy-6-nitro-octyl ester

There total 3 articles about Acetic acid (1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5-hydroxy-6-nitro-octyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 51146-38-4
C₆H₁₅NO₂Si

: 127239-26-3
5-O-acetyl-2,3,4,6-tetra-O-benzyl-aldehydo-D-glucose

: 127263-08-5
Acetic acid (1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5-hydroxy-6-nitro-octyl ester

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; -78 deg C, 3 h; room temp., 12 h;
DOI:10.1016/S0040-4039(01)93325-8

Reference yield:

: 4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9
2,3,4,6-Tetra-O-benzyl-D-glucopyranose

: 127263-08-5
Acetic acid (1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5-hydroxy-6-nitro-octyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) conc. HCl, 2.) pyridine

2: 73 percent / HgO/HgCl₂ / acetone; H₂O

3: 75 percent / nBu₄NF / tetrahydrofuran / -78 deg C, 3 h; room temp., 12 h

With pyridine; hydrogenchloride; tetrabutyl ammonium fluoride; mercury dichloride; mercury(II) oxide; In tetrahydrofuran; water; acetone;
DOI:10.1016/S0040-4039(01)93325-8

Reference yield:

: 53929-49-0
Acetic acid (1R,2R,3S,4R)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5,5-bis-ethylsulfanyl-pentyl ester

: 127263-08-5
Acetic acid (1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5-hydroxy-6-nitro-octyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 73 percent / HgO/HgCl₂ / acetone; H₂O

2: 75 percent / nBu₄NF / tetrahydrofuran / -78 deg C, 3 h; room temp., 12 h

With tetrabutyl ammonium fluoride; mercury dichloride; mercury(II) oxide; In tetrahydrofuran; water; acetone;
DOI:10.1016/S0040-4039(01)93325-8