MeC(2-C₅H₄N)(CH₂NH(4-C₆H₄Me))2

Base Information

• Chemical Name: MeC(2-C₅H₄N)(CH₂NH(4-C₆H₄Me))2
• CAS No.: 526200-10-2
• Molecular Formula: C₂₃H₂₇N₃
• Molecular Weight: 345.487
• Mol file: 526200-10-2.mol

Synonyms:MeC(2-C₅H₄N)(CH₂NH(4-C₆H₄Me))2

Chemical Property of MeC(2-C₅H₄N)(CH₂NH(4-C₆H₄Me))2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of MeC(2-C₅H₄N)(CH₂NH(4-C₆H₄Me))2

There total 1 articles about MeC(2-C₅H₄N)(CH₂NH(4-C₆H₄Me))2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

para-bromotoluene (106-38-7) + 2-methyl-2-(pyridin-2-yl)propane-1,3-diamine (199984-52-6) → MeC(2-C5H4N)(CH2NH(4-C6H4Me))2 (526200-10-2)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; In toluene; at 110 ℃; for 24h;

DOI:10.1039/b209382k

Reference yield: 87.0%

tetrakis(dimethylamido)titanium(IV) + MeC(2-C5H4N)(CH2NH(4-C6H4Me))2 (526200-10-2) → [Ti(MeC(2-C5H4N)(CH2N-4-C6H4Me)2)(NMe2)2] (959627-77-1)

Guidance literature:

In neat (no solvent); placed under partial vac., stirred overnight at 100°C; washed (pentane), dried (vac.); elem. anal.;

DOI:10.1021/om700758v

Reference yield: 68.0%

[scandium tris(trimethylsilylmethyl)(THF)2] (41705-65-1) + MeC(2-C5H4N)(CH2NH(4-C6H4Me))2 (526200-10-2) → Sc(C5H4NCCH3(CH2NC6H4CH3)2)CH2Si(CH3)3(C4H8O) (526200-02-2)

Guidance literature:

In benzene; a soln. of complex in benzene was added dropwise to a soln. of diamine in benzene at 7°C, allowed to warm to room temp. and stirred for 1h (inert atm.); volatiles were removed under reduced pressure; elem. anal.;

DOI:10.1039/b209382k

upstream raw materials:

para-bromotoluene

2-methyl-2-(pyridin-2-yl)propane-1,3-diamine

Downstream raw materials:

Sc(C₅H₄NCCH₃(CH₂NC₆H₄CH₃)2)CH₂Si(CH₃)3(C₄H₈O)

[Ti(MeC(2-C₅H₄N)(CH₂N-4-C₆H₄Me)2)(NMe₂)2]