4-Allyloxy-1-butanol

Base Information

• Chemical Name: 4-Allyloxy-1-butanol
• CAS No.: 1471-15-4
• Molecular Formula: C7H14 O2
• Molecular Weight: 130.187
• Hs Code.: 2909499000
• European Community (EC) Number: 828-413-9
• DSSTox Substance ID: DTXSID80460769
• Nikkaji Number: J1.182.458G
• Wikidata: Q82284918
• Mol file: 1471-15-4.mol

Synonyms:1471-15-4;4-allyloxy-1-butanol;4-prop-2-enoxybutan-1-ol;4-(PROP-2-EN-1-YLOXY)BUTAN-1-OL;1-Butanol, 4-(2-propen-1-yloxy)-;4-HYDROXYBUTYL-1-ALLYLETHER;4-allyloxybutanol-1;SCHEMBL108956;DTXSID80460769;CTDRAOLVEHKAAZ-UHFFFAOYSA-N;BAA47115;EN300-365834

Chemical Property of 4-Allyloxy-1-butanol

Chemical Property:

• PSA: 29.46000
• LogP: 0.96150
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 130.099379685
• Heavy Atom Count: 9
• Complexity: 61.9

Purity/Quality:

98% ^*data from raw suppliers

4-(prop-2-en-1-yloxy)butan-1-ol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCOCCCCO

Technology Process of 4-Allyloxy-1-butanol

There total 9 articles about 4-Allyloxy-1-butanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

1-allyloxy-4-(tert-butyldimethylsilyloxy)butane (209254-31-9) → 4-allyloxybutan-1-ol (1471-15-4)

Guidance literature:

With zirconium(IV) chloride; In acetonitrile; at 20 ℃; for 0.5h;

DOI:10.1016/S0040-4039(03)01088-8

Reference yield: 91.0%

1-((4-(allyloxy)butoxy)methyl)-4-methoxybenzene → 4-allyloxybutan-1-ol (1471-15-4)

Guidance literature:

With trichlorophosphate; In 1,2-dichloro-ethane; at 20 ℃; for 0.833333h;

DOI:10.1039/c3ra42113a

Reference yield: 82.0%

1-allyloxy-4-(tetrahydropyran-2-yloxy)butane (209254-39-7) → 4-allyloxybutan-1-ol (1471-15-4)

Guidance literature:

With methanol; Montmorillonite K-10 clay; at 20 ℃;

DOI:10.1055/s-1999-2822

upstream raw materials:

Butane-1,4-diol

3-chloroprop-1-ene

allyl n-butyl ether

allyl bromide

Downstream raw materials:

(2S,3S,4R,5R,6S)-2-[(1R,2R)-2-(4-Allyloxy-butoxy)-cyclohexyloxy]-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran

(4S)-methyl-(5R)-phenyl-3-(4-propenyloxy-(2S)-methyl-butanoyl)-oxazolidin-2-one

(4R)-methyl-(5S)-phenyl-3-(4-propenyloxy-2(R)-methyl-butanoyl)-oxazolidin-2-one

(4R)-methyl-(5S)-phenyl-3-(4-propenyloxy)butanoyloxazolidin-2-one

Refernces

• 1、 Prosser,T.J.. "-". . p. 1701 - 1704. Retrieved 1961.
• 2、 Ilangovan, Andivelu,Anandhan, Karnambaram,Kaushik, Mahabir Prasad. "Facile and selective deprotection of PMB ethers and esters using oxalyl chloride". . p. 1081 - 1084. Retrieved 2015/02/19.
• 3、 Cheng, Yi An,Chen, Tao,Tan, Chong Kiat,Heng, Jun Jie,Yeung, Ying-Yeung. "Efficient medium ring size bromolactonization using a sulfur-based zwitterionic organocatalyst". supporting information. p. 16492 - 16495,4. Retrieved 2020/09/15.