[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(trihexylsilylbutadiynyl)porphynato]nickel(II)

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Chemical Name:[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(trihexylsilylbutadiynyl)porphynato]nickel(II)
CAS No.:1244778-18-4
Molecular Formula:C₇₆H₉₄N₄NiSi
Molecular Weight:1150.38
Hs Code.:

Synonyms:[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(trihexylsilylbutadiynyl)porphynato]nickel(II)

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Chemical Property of [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(trihexylsilylbutadiynyl)porphynato]nickel(II)

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Technology Process of [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(trihexylsilylbutadiynyl)porphynato]nickel(II)

There total 1 articles about [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(trihexylsilylbutadiynyl)porphynato]nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1050506-23-4
mono(trihexylsilyl)acetylene

: 952190-21-5
[Ni((3,5-di-tert-butylphenyl)2(Ph)(HCC)C₂₀H₈N₄)]

: 1244778-18-4
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(trihexylsilylbutadiynyl)porphynato]nickel(II)

Guidance literature:: With CuCl; (CH₃)2NCH₂CH₂N(CH₃)2; air; In tetrahydrofuran; CH₂Cl₂; stirring soln. of porpyrin deriv. and silylacetylene deriv. in CH2Cl2 and THF under dry air, addn. of copper chloride and amine deriv., stirringfor 4 h; filtration through silica, chromy. (silica gel, light petroleum ether/CH2Cl2 (10:1)) under N2, NMR and MS;
DOI:10.1039/c003715j

Reference yield: 100.0%

: 1244778-18-4
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(trihexylsilylbutadiynyl)porphynato]nickel(II)

: 1309441-71-1
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II)

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; at 20 ℃; for 0.25h; Inert atmosphere;
DOI:10.1039/c003715j