5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin bisNi(II)

Base Information

• Chemical Name: 5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin bisNi(II)
• CAS No.: 1573176-49-4
• Molecular Formula: C₉₆H₁₀₆N₈Ni₂Si₂
• Molecular Weight: 1545.5
• Mol file: 1573176-49-4.mol

Synonyms:5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin bisNi(II)

Chemical Property of 5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin bisNi(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin bisNi(II)

There total 1 articles about 5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin bisNi(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

10-bromo-5,15-bis(triisopropylsilylethynyl)porphyrin Ni(II) (1573176-45-0) + 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II) (1573176-69-8) → 5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin bisNi(II) (1573176-49-4)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; caesium carbonate; triphenylphosphine; In water; N,N-dimethyl-formamide; toluene; at 100 ℃; for 3h; Schlenk technique; Inert atmosphere;

DOI:10.1021/ol500569b

Reference yield: 58.0%

5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin bisNi(II) (1573176-49-4) → 5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}porphyrin bisNi(II) (1573176-54-1)

Guidance literature:

5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin bisNi(II); With tetrabutyl ammonium fluoride; In tetrahydrofuran; at -40 ℃; for 0.166667h; Schlenk technique; Inert atmosphere;

With para-dodecylbenzenesulfonic acid; In water; 1,2-dichloro-ethane; at 80 ℃; for 16h;

DOI:10.1021/ol500569b

upstream raw materials:

10-bromo-5,15-bis(triisopropylsilylethynyl)porphyrin Ni(II)

5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)

Downstream raw materials:

5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}porphyrin bisNi(II)