5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)

Base Information

• Chemical Name: 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)
• CAS No.: 1573176-69-8
• Molecular Formula: C₆₀H₆₇BN₄NiO₂
• Molecular Weight: 945.719
• Mol file: 1573176-69-8.mol

Synonyms:5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)

Chemical Property of 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)

There total 1 articles about 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

5-bromo-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II) (545432-83-5) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II) (1573176-69-8)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; triethylamine; In 1,2-dichloro-ethane; at 75 ℃; for 5h; Schlenk technique; Inert atmosphere;

DOI:10.1021/ol500569b

Reference yield: 58.0%

10-bromo-5,15-bis(triisopropylsilylethynyl)porphyrin Ni(II) (1573176-45-0) + 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II) (1573176-69-8) → 5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin bisNi(II) (1573176-49-4)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; caesium carbonate; triphenylphosphine; In water; N,N-dimethyl-formamide; toluene; at 100 ℃; for 3h; Schlenk technique; Inert atmosphere;

DOI:10.1021/ol500569b

Reference yield: 57.0%

5,15-dibromo-10,20-bis(triisopropylsilylethynyl)porphyrin Ni(II) (1573176-47-2) + 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II) (1573176-69-8) → 5,15-bis{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin trisNi(II) (1573176-52-9)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; caesium carbonate; triphenylphosphine; In water; N,N-dimethyl-formamide; toluene; at 100 ℃; for 3h; Schlenk technique; Inert atmosphere;

DOI:10.1021/ol500569b

upstream raw materials:

5-bromo-15-phenyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

Downstream raw materials:

5-{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin bisNi(II)

5,15-bis{5,15-bis(3,5-di-tert-butylphenyl)-10-phenylporphyrin-20-yl}-10,20-bis(triisopropylsilylethynyl)porphyrin trisNi(II)