[Fe(η2-OCNiPr2)(CO)2(PPh3)2](O2CCF3)

Base Information

Chemical Name:[Fe(η2-OCNiPr2)(CO)2(PPh3)2](O2CCF3)
CAS No.:164072-10-0
Molecular Formula:C₂F₃O₂*C₄₅H₄₄FeNO₃P₂
Molecular Weight:877.66
Hs Code.:

Synonyms:[Fe(η2-OCNiPr2)(CO)2(PPh3)2](O2CCF3)

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Chemical Property of [Fe(η2-OCNiPr2)(CO)2(PPh3)2](O2CCF3)

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Technology Process of [Fe(η2-OCNiPr2)(CO)2(PPh3)2](O2CCF3)

There total 4 articles about [Fe(η2-OCNiPr2)(CO)2(PPh3)2](O2CCF3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 13463-40-6,71564-23-3,37220-42-1
iron pentacarbonyl

: 603-35-0
triphenylphosphine

: 407-25-0
trifluoroacetic anhydride

: 4111-54-0
lithium diisopropyl amide

: 164072-10-0
[Fe(η2-OCNiPr2)(CO)2(PPh3)2](O2CCF3)

: 2923-17-3
lithium trifluoroacetate

Guidance literature:: In diethyl ether; under N2 atm. to soln. (Fe(CO)5) in Et2O LDA was added dropwise, react.was cooled (dry ice/propanone) and (CF3CO)2O in Et2O was added and mixt. was stirred at low temp. for 15 min, PPh3 was added and react. was allowed to warm to room temp. overnight; react. was cooled to room temp., soln. was filtered, solvent was removed under reduced pressure, residue was extd. with mixt. propanone and light petroleum, extracts were concd. and cooled, crystals were dried in vacuo; elem. anal.;
DOI:10.1021/om990385y

Reference yield: 13.0%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 603-35-0
triphenylphosphine

: 407-25-0
trifluoroacetic anhydride

: 4111-54-0
lithium diisopropyl amide

: 164072-10-0
[Fe(η2-OCNiPr2)(CO)2(PPh3)2](O2CCF3)

: 164072-08-6
[Fe(CNiPr₂)(CO)3(PPh₃)]O₂CCF₃

Guidance literature:: In diethyl ether; dichloromethane; N2-atmosphere; stirring (15 min), PPh3 addn.; petroleum ether addn., filtering, concg. (-30°C), filtering, washing (THF), petroleum ether addn. (-30°C);
DOI:10.1021/om00004a007

Reference yield: 12.5%

: 13463-40-6,71564-23-3,37220-42-1
iron pentacarbonyl

: 603-35-0
triphenylphosphine

: 407-25-0
trifluoroacetic anhydride

: 4111-54-0
lithium diisopropyl amide

: 164072-10-0
[Fe(η2-OCNiPr2)(CO)2(PPh3)2](O2CCF3)

: 164072-08-6
[Fe(CNiPr₂)(CO)3(PPh₃)]O₂CCF₃

Guidance literature:: In diethyl ether; under N2 atm. to soln. (Fe(CO)5) in Et2O LDA was added, react. mixt. was cooled in dry ice/propanone bath, (CF3CO)2O was added dropwise, react.mixt. was stirred for 15 min, PPh3 was added, and mixt. allowed to warmto room temp. overnight; petrol (40-60) was added, ract. mixt. was filtered, ppt. was collected,extracted into THF, extracts were filtered, solvent was removed under reduced pressure; elem. anal.;
DOI:10.1021/om990385y