benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone

Base Information

Chemical Name:benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone
CAS No.:1271132-21-8
Molecular Formula:C₆₂H₆₁ClN₄O₁₆S
Molecular Weight:1185.7
Hs Code.:

benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone

Synonyms:benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone

Suppliers and Price of benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone

There total 1 articles about benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 1154464-02-4
phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone

: 1271132-19-4
benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-D-galactopyranosyl N-phenyltrifluoroacetimidate

: benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-β-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone

: 1271132-21-8
benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone

Guidance literature:: phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone; benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-D-galactopyranosyl N-phenyltrifluoroacetimidate; In dichloromethane; for 0.5h; Molecular sieve;

With trifluorormethanesulfonic acid; In dichloromethane; at 0 ℃; for 0.5h; optical yield given as %de; diastereoselective reaction;
DOI:10.1021/jo102363d

Reference yield: 81.0%

: 1271132-21-8
benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone

: 20196-71-8
(2S)-2,3-bis(benzyloxy)propanol

: 1271132-23-0
benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-2-O-benzyl-α-D-galactopyranosiduronyl-3,6-lactone-(1->3)-1,2-di-O-benzyl-sn-glycerol

Guidance literature:: benzyl 2,4-di-O-benzyl-3-O-chloroacetyl-α-D-galactopyranosyluronate-(1->3)-4-(N-benzyloxycarbonylamino)-2-azido-2,4,6-trideoxy-α-D-galactopyranosyl-(1->4)-phenyl 2-O-benzyl-1-thio-β-D-galactopyranosidurono-3,6-lactone; With 1,1'-sulfinylbisbenzene; 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; for 0.5h; Molecular sieve;

With trifluoromethylsulfonic anhydride; In dichloromethane; at -60 - -45 ℃;

(2S)-2,3-bis(benzyloxy)propanol; With 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; at -60 - -45 ℃; diastereoselective reaction;
DOI:10.1021/jo102363d