3,3''-DINITRO-2,2''-DIPYRIDYL

Base Information

• Chemical Name: 3,3''-DINITRO-2,2''-DIPYRIDYL
• CAS No.: 1024-94-8
• Molecular Formula: C10H6 N4 O4
• Molecular Weight: 246.182
• Hs Code.: 2933399090
• Mol file: 1024-94-8.mol

Synonyms:3,3'-Dinitro-2,2'-bipyridine

Chemical Property of 3,3''-DINITRO-2,2''-DIPYRIDYL

Chemical Property:

• Boiling Point: 396.8°Cat760mmHg
• Flash Point: 193.8°C
• PSA: 117.42000
• Density: 1.493g/cm³
• LogP: 3.00640

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3,3''-DINITRO-2,2''-DIPYRIDYL

There total 7 articles about 3,3''-DINITRO-2,2''-DIPYRIDYL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

2-Chloro-3-nitropyridine (5470-18-8,34515-82-7) → 3,3’-dinitro-2,2’-bipyridine (1024-94-8)

Guidance literature:

With copper; In N,N-dimethyl-formamide; at 150 ℃; for 2h;

DOI:10.1080/00397919708004101

Reference yield: 50.0%

2-Chloro-3-nitropyridine (5470-18-8,34515-82-7) + 4-chloro-3-nitropyridine (13091-23-1) → 3,3'-dinitro-2,4'-bipyridyl (81330-16-7) + 3,3’-dinitro-2,2’-bipyridine (1024-94-8) + 3-nitro-4-(3-nitro-4-pyridyl)pyridine (54356-26-2)

Guidance literature:

With copper; In N,N-dimethyl-formamide; at 130 ℃; for 14h;

DOI:10.1016/S0040-4039(01)93037-0

Reference yield: 50.0%

4-chloro-3-nitropyridine (13091-23-1) → 3,3'-dinitro-2,4'-bipyridyl (81330-16-7) + 3,3’-dinitro-2,2’-bipyridine (1024-94-8) + 3-nitro-4-(3-nitro-4-pyridyl)pyridine (54356-26-2)

Guidance literature:

With 2-Chloro-3-nitropyridine; copper bronze; In N,N-dimethyl-formamide; at 130 ℃; for 14h;

upstream raw materials:

2-Chloro-3-nitropyridine

2-chloro-5-methyl-3-nitro-pyridine

2-nitrophenyl bromide

4-chloro-3-nitropyridine

Downstream raw materials:

C₄₄H₄₀N₆O₆

(2S,2'S)-N,N'-([2,2'-bipyridine]-3,3'-diyl)bis(2-amino-3-phenylpropanamide)

N₃,N₃'-bis(diphenylphosphino)-2,2'-bipyridine-3,3'-diamine

[C₁₀H₆N₂{PPh₂NHRh(cod)Cl}₂]

Refernces

• 1、 Zhang, Huimiao,Toy, Patrick H.. "Halogen Bond-Catalyzed Friedel?Crafts Reactions of Furans Using a 2,2’-Bipyridine-Based Catalyst". . p. 215 - 221. Retrieved 2021.
• 2、 Zhao, Hongwu,Yue, Yuanyuan,Li, Hailong,Sheng, Zhihui,Yang, Zhao,Meng, Wei. "Asymmetric synthesis of novel axially chiral 2,2′-bipyridine n,n′-dioxides bearing α-amino acid residues and their applications in enantioselective allylation of aromatic aldehydes with allyltrichlorosilane". . p. 485 - 493. Retrieved 2013/08/25.