bis(η5-cyclopentadienyl)p-tolyl{(phenylthio)(trimethylsilyl)methyl}zirconium

Base Information

Chemical Name:bis(η5-cyclopentadienyl)p-tolyl{(phenylthio)(trimethylsilyl)methyl}zirconium
CAS No.:111005-12-0
Molecular Formula:C₂₇H₃₂SSiZr
Molecular Weight:507.927
Hs Code.:

Synonyms:bis(η5-cyclopentadienyl)p-tolyl{(phenylthio)(trimethylsilyl)methyl}zirconium

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Chemical Property of bis(η5-cyclopentadienyl)p-tolyl{(phenylthio)(trimethylsilyl)methyl}zirconium

Chemical Property:

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Technology Process of bis(η5-cyclopentadienyl)p-tolyl{(phenylthio)(trimethylsilyl)methyl}zirconium

There total 1 articles about bis(η5-cyclopentadienyl)p-tolyl{(phenylthio)(trimethylsilyl)methyl}zirconium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 102493-94-7
bis(η5-cyclopentadienyl){(phenylthio)(trimethylsilyl)methyl}zirconium(Cl)

: 106-38-7
para-bromotoluene

: 7439-95-4
magnesium

: 111005-12-0
bis(η5-cyclopentadienyl)p-tolyl{(phenylthio)(trimethylsilyl)methyl}zirconium

Guidance literature:: In diethyl ether; Under protective gas, dropwise addn. of p-tolylmagnesiumbromide (prepd. from 4-bromotoluene and excess Mg in ether) to a suspn. of Cp2ZrCl(CH(Si(CH3)3)SC6H5) in ether at room temp., stirring of mixt. overnight in the dark.; Evapn., extn. of residue twice with pentane, evapn., elem. anal..;

Reference yield:

: 111005-12-0
bis(η5-cyclopentadienyl)p-tolyl{(phenylthio)(trimethylsilyl)methyl}zirconium

: 111005-10-8
bis(η5-cyclopentadienyl)zirconium{C(2)H(thiophenyl)(trimethylsilyl)}

: benzyltrimethylsilane-d1

: 770-09-2
benzyltrimethylsilane

: 7450-04-6
1-((trimethylsilyl)methyl)-4-methylbenzene

: 120059-91-8
p-xylyltrimethylsilane-d1

Guidance literature:: With hydrogenchloride; In ⁽²⁾H₈-toluene; Under protective gas, thermolysis in toluene at 82°C for 48 h followed by hydrolysis with HCl.; Centrifugation, seperation, evapn. of org. layer, GC/MS.;

Reference yield:

: 111005-12-0
bis(η5-cyclopentadienyl)p-tolyl{(phenylthio)(trimethylsilyl)methyl}zirconium

: 7450-04-6
1-((trimethylsilyl)methyl)-4-methylbenzene

Guidance literature:: With hydrogenchloride; In ⁽²⁾H₈-toluene; Soln. of Cp2Zr(p-CH3C6H4)(CH(SC6H5)(Si(CH3)3)) is thermolyzed in sealed NMR-tube at 82°C under protective gas, after 12 h tube is broken, addn. of conc. HCl.; Monitored by (1)H-NMR, mixing of layers, sepg. of org. layer, vac. distn., NMR and GC/MS.; Kinetics;