Silane, trimethyl[(4-methylphenyl)methyl]-

Base Information

• Chemical Name: Silane, trimethyl[(4-methylphenyl)methyl]-
• CAS No.: 7450-04-6
• Molecular Formula: C11H18Si
• Molecular Weight: 178.349
• Mol file: 7450-04-6.mol

Synonyms:p-xylyltrimethylsilane;trimethyl((4-methylphenyl)methyl)silane;4-methylbenzyltrimethylsilane;trimethyl(4-methylbenzyl)silane;Trimethyl-(4-methyl-benzyl)-silan;

Chemical Property of Silane, trimethyl[(4-methylphenyl)methyl]-

Chemical Property:

• PSA: 0.00000
• LogP: 3.68130

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, trimethyl[(4-methylphenyl)methyl]-

There total 14 articles about Silane, trimethyl[(4-methylphenyl)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

4-tolyl iodide (624-31-7) + tris{(trimethylsilyl)methyl}indium (69833-15-4) → 1-((trimethylsilyl)methyl)-4-methylbenzene (7450-04-6)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; for 2h; Heating;

DOI:10.1021/ja004195m

Reference yield: 83.0%

<4-chlorophenylthio(4-methylphenyl)methyl>trimethylsilane (103559-10-0) → 1-((trimethylsilyl)methyl)-4-methylbenzene (7450-04-6)

Guidance literature:

With nickel; In ethanol; for 3h; Heating;

Reference yield: 76.0%

chloro-trimethyl-silane (75-77-4) + 4-Methylbenzyl chloride (104-82-5) → 1-((trimethylsilyl)methyl)-4-methylbenzene (7450-04-6)

Guidance literature:

With tetraethylammonium tosylate; In N,N-dimethyl-formamide; electrochemical reduction using diaphragm;

DOI:10.1246/cl.1985.463

upstream raw materials:

chloro-trimethyl-silane

<4-chlorophenylthio(4-methylphenyl)methyl>trimethylsilane

4-Methylbenzyl chloride

para-xylene

Downstream raw materials:

1-(tert-butoxymethyl)-4-methylbenzene

4-methyl-benzaldehyde

4-Methylbenzyl chloride

para-xylene

Refernces

• 1、 Przyojski, Jacob A.,Arman, Hadi D.,Tonzetich, Zachary J.. "NHC complexes of cobalt(II) relevant to catalytic C-C coupling reactions". . p. 723 - 732. Retrieved 2013/03/28.
• 2、 Dockery, Kevin P.,Dinnocenzo, Joseph P.,Farid, Samir,Goodman, Joshua L.,Gould, Ian R.,Todd, William P.. "Nucleophile-assisted cleavage of benzyltrialkylsilane cation radicals". . p. 1876 - 1883. Retrieved 2007/10/03.