(1R,2R)-1-formyl-2-<(Z)-hex-1-enyl>cyclopropane

Base Information

Chemical Name:(1R,2R)-1-formyl-2-<(Z)-hex-1-enyl>cyclopropane
CAS No.:106137-58-0
Molecular Formula:C₁₀H₁₆O
Molecular Weight:152.236
Hs Code.:

Synonyms:(1R,2R)-1-formyl-2-<(Z)-hex-1-enyl>cyclopropane

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Chemical Property of (1R,2R)-1-formyl-2-<(Z)-hex-1-enyl>cyclopropane

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Technology Process of (1R,2R)-1-formyl-2-<(Z)-hex-1-enyl>cyclopropane

There total 7 articles about (1R,2R)-1-formyl-2-<(Z)-hex-1-enyl>cyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 826-34-6
dimethyl cis-cyclopropane-1,2-dicarboxylate

: 106137-58-0
(1R,2R)-1-formyl-2-<(Z)-hex-1-enyl>cyclopropane

Guidance literature:: Multi-step reaction with 7 steps

1: LAH / diethyl ether / 0.5 h / 0 °C

2: DMAP, TEA / CH₂Cl₂ / 1 h / Ambient temperature

3: 1M NaOH / ethane-1,2-diol; H₂O / 3 °C / lipase (PPL)

4: PCC, NaOAc, molecular sieves / CH₂Cl₂ / 1 h / Ambient temperature

5: 2) HMPT / 1) THF, -30 deg C to room temp., 20 min, 2) THF, -65 deg C to room temp.

6: 92 percent / K₂CO₃, MeOH / 0.25 h / Ambient temperature

7: PCC, NaOAc, molecular sieves / CH₂Cl₂ / 0.5 h / Ambient temperature

With methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; sodium hydroxide; lithium aluminium tetrahydride; molecular sieve; TEA; sodium acetate; potassium carbonate; pyridinium chlorochromate; In diethyl ether; dichloromethane; water; ethylene glycol;
DOI:10.1016/S0040-4020(01)86378-X

Reference yield:

: 106137-57-9
(1R,2R)-1-<(Z)-hex-1-enyl>-2-hydroxymethylcyclopropane

: 106137-58-0
(1R,2R)-1-formyl-2-<(Z)-hex-1-enyl>cyclopropane

Guidance literature:: With molecular sieve; sodium acetate; pyridinium chlorochromate; In dichloromethane; for 0.5h; Yield given; Ambient temperature;
DOI:10.1016/S0040-4020(01)86378-X

Reference yield:

: 2345-68-8,192056-11-4
((1R,2S)-2-Hydroxymethyl-cyclopropyl)-methanol

: 106137-58-0
(1R,2R)-1-formyl-2-<(Z)-hex-1-enyl>cyclopropane

Guidance literature:: Multi-step reaction with 6 steps

1: DMAP, TEA / CH₂Cl₂ / 1 h / Ambient temperature

2: 1M NaOH / ethane-1,2-diol; H₂O / 3 °C / lipase (PPL)

3: PCC, NaOAc, molecular sieves / CH₂Cl₂ / 1 h / Ambient temperature

4: 2) HMPT / 1) THF, -30 deg C to room temp., 20 min, 2) THF, -65 deg C to room temp.

5: 92 percent / K₂CO₃, MeOH / 0.25 h / Ambient temperature

6: PCC, NaOAc, molecular sieves / CH₂Cl₂ / 0.5 h / Ambient temperature

With methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; sodium hydroxide; molecular sieve; TEA; sodium acetate; potassium carbonate; pyridinium chlorochromate; In dichloromethane; water; ethylene glycol;
DOI:10.1016/S0040-4020(01)86378-X