(4R,5S)-5-(4-methanesulfonyloxy-3-methoxy)phenyl-4-{[(4-methanesulfonyloxy-3-methoxybenzyl)oxy]methyl}-3-acetyltetrahydro-2-furanone

Base Information

Chemical Name:(4R,5S)-5-(4-methanesulfonyloxy-3-methoxy)phenyl-4-{[(4-methanesulfonyloxy-3-methoxybenzyl)oxy]methyl}-3-acetyltetrahydro-2-furanone
CAS No.:651779-94-1
Molecular Formula:C₂₄H₂₈O₁₂S₂
Molecular Weight:572.611
Hs Code.:

Synonyms:(4R,5S)-5-(4-methanesulfonyloxy-3-methoxy)phenyl-4-{[(4-methanesulfonyloxy-3-methoxybenzyl)oxy]methyl}-3-acetyltetrahydro-2-furanone

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Chemical Property of (4R,5S)-5-(4-methanesulfonyloxy-3-methoxy)phenyl-4-{[(4-methanesulfonyloxy-3-methoxybenzyl)oxy]methyl}-3-acetyltetrahydro-2-furanone

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Technology Process of (4R,5S)-5-(4-methanesulfonyloxy-3-methoxy)phenyl-4-{[(4-methanesulfonyloxy-3-methoxybenzyl)oxy]methyl}-3-acetyltetrahydro-2-furanone

There total 5 articles about (4R,5S)-5-(4-methanesulfonyloxy-3-methoxy)phenyl-4-{[(4-methanesulfonyloxy-3-methoxybenzyl)oxy]methyl}-3-acetyltetrahydro-2-furanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: p-(hydroxymethyl)-2-methoxyphenyl methanesulfonate

: 651779-87-2
(1R,4S,5S)-1-acetyl-4-(4-methanesulfonyloxy-3-methoxyphenyl)-3-oxabicyclo[3.1.0]hexan-2-one

: 651779-94-1
(4R,5S)-5-(4-methanesulfonyloxy-3-methoxy)phenyl-4-{[(4-methanesulfonyloxy-3-methoxybenzyl)oxy]methyl}-3-acetyltetrahydro-2-furanone

Guidance literature:: With 2,6-di-tert-butyl-pyridine; magnesium(II) perchlorate; at 120 ℃; for 2.5h;
DOI:10.1021/jo035365r

Reference yield:

: 52200-05-2
4-methanesulfonyloxy-3-methoxybenzaldehyde

: 651779-94-1
(4R,5S)-5-(4-methanesulfonyloxy-3-methoxy)phenyl-4-{[(4-methanesulfonyloxy-3-methoxybenzyl)oxy]methyl}-3-acetyltetrahydro-2-furanone

Guidance literature:: Multi-step reaction with 5 steps

1: tetrahydrofuran / -60 - -10 °C

2: 39 percent / Novozyme 435 / 17 h / 40 °C

3: 92 percent / xylene / 0.25 h / 150 °C

4: Mn(OAc)3*2H₂O; Cu(OAc)2; KOAc / acetic acid / 0.25 h / 70 °C

5: 72 percent / 2,6-di-tert-butylpyridine; Mg(ClO₄)2 / 2.5 h / 120 °C

With 2,6-di-tert-butyl-pyridine; magnesium(II) perchlorate; copper diacetate; novozyme 435; potassium acetate; manganese triacetate; In tetrahydrofuran; acetic acid; xylene;
DOI:10.1021/jo035365r

Reference yield:

: 651779-84-9
1-(4-methanesulfonyloxy-3-methoxyphenyl)prop-2-en-1-ol

: 651779-94-1
(4R,5S)-5-(4-methanesulfonyloxy-3-methoxy)phenyl-4-{[(4-methanesulfonyloxy-3-methoxybenzyl)oxy]methyl}-3-acetyltetrahydro-2-furanone

Guidance literature:: Multi-step reaction with 4 steps

1: 39 percent / Novozyme 435 / 17 h / 40 °C

2: 92 percent / xylene / 0.25 h / 150 °C

3: Mn(OAc)3*2H₂O; Cu(OAc)2; KOAc / acetic acid / 0.25 h / 70 °C

4: 72 percent / 2,6-di-tert-butylpyridine; Mg(ClO₄)2 / 2.5 h / 120 °C

With 2,6-di-tert-butyl-pyridine; magnesium(II) perchlorate; copper diacetate; novozyme 435; potassium acetate; manganese triacetate; In acetic acid; xylene;
DOI:10.1021/jo035365r