2,3-dihydro-[B-2-(E)-1-phenylethen-1-yl]-1H-naphtho[1,8-de]-[1,3,2]-diazaborine

Base Information

Chemical Name:2,3-dihydro-[B-2-(E)-1-phenylethen-1-yl]-1H-naphtho[1,8-de]-[1,3,2]-diazaborine
CAS No.:1147458-75-0
Molecular Formula:C₁₈H₁₅BN₂
Molecular Weight:270.142
Hs Code.:

Synonyms:2,3-dihydro-[B-2-(E)-1-phenylethen-1-yl]-1H-naphtho[1,8-de]-[1,3,2]-diazaborine

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Chemical Property of 2,3-dihydro-[B-2-(E)-1-phenylethen-1-yl]-1H-naphtho[1,8-de]-[1,3,2]-diazaborine

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Technology Process of 2,3-dihydro-[B-2-(E)-1-phenylethen-1-yl]-1H-naphtho[1,8-de]-[1,3,2]-diazaborine

There total 11 articles about 2,3-dihydro-[B-2-(E)-1-phenylethen-1-yl]-1H-naphtho[1,8-de]-[1,3,2]-diazaborine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 6783-05-7
trans-2-phenylvinylboronic acid

: 479-27-6
naphthalene-1,8-diamine

: 1147458-75-0
2,3-dihydro-[B-2-(E)-1-phenylethen-1-yl]-1H-naphtho[1,8-de]-[1,3,2]-diazaborine

Guidance literature:: With 1H-imidazole; iron(III) chloride; In water; acetonitrile; at 20 ℃; for 2h; Inert atmosphere;
DOI:10.1055/s-0033-1340500

Reference yield: 91.0%

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 5656-71-3
2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

: 1147458-75-0
2,3-dihydro-[B-2-(E)-1-phenylethen-1-yl]-1H-naphtho[1,8-de]-[1,3,2]-diazaborine

Guidance literature:: With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; In 1,4-dioxane; at 60 ℃; for 4h; optical yield given as %de; stereoselective reaction; Inert atmosphere;
DOI:10.1246/cl.2010.558

Reference yield: 91.0%

: 1214264-88-6
2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

: 536-74-3
phenylacetylene

: 1147458-75-0
2,3-dihydro-[B-2-(E)-1-phenylethen-1-yl]-1H-naphtho[1,8-de]-[1,3,2]-diazaborine

Guidance literature:: With [Cu(phen)(xantphosTEPD)]PF₆; potassium carbonate; In water; acetonitrile; at 20 ℃; for 7h; diastereoselective reaction; Sealed tube; Inert atmosphere; Irradiation;
DOI:10.1002/anie.202101874