(-)-albicanyl 3,4-dihydroxycinnamate

Base Information

• Chemical Name: (-)-albicanyl 3,4-dihydroxycinnamate
• CAS No.: 80357-99-9
• Molecular Formula: C₂₄H₃₂O₄
• Molecular Weight: 384.516
• Mol file: 80357-99-9.mol

Synonyms:(-)-albicanyl 3,4-dihydroxycinnamate

Chemical Property of (-)-albicanyl 3,4-dihydroxycinnamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (-)-albicanyl 3,4-dihydroxycinnamate

There total 5 articles about (-)-albicanyl 3,4-dihydroxycinnamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(-)-albicanyl 3,4-diacetoxycinnamate → (-)-albicanyl 3,4-dihydroxycinnamate (80357-99-9)

Guidance literature:

With lipase Amano P; In di-isopropyl ether; water; at 35 ℃; for 1h;

DOI:10.1016/S0957-4166(00)00076-8

Reference yield:

caffeic acid (331-39-5,501-16-6) → (-)-albicanyl 3,4-dihydroxycinnamate (80357-99-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 93 percent / pyridine / 1 h / 20 °C

2: 50 percent / DCC; DMAP; (+)-CSA / CH₂Cl₂ / 12 h / 20 °C

3: 99 percent / lipase Amano P / H₂O; diisopropyl ether / 1 h / 35 °C

With pyridine; dmap; lipase Amano P; (1S)-10-camphorsulfonic acid; dicyclohexyl-carbodiimide; In dichloromethane; di-isopropyl ether; water; 1: Acetylation / 2: Esterification / 3: Deacetylation;

DOI:10.1016/S0957-4166(00)00076-8

Reference yield:

(8aS)-(+)-albicanol (54632-04-1,104758-36-3,104758-37-4,112709-43-0) → (-)-albicanyl 3,4-dihydroxycinnamate (80357-99-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 50 percent / DCC; DMAP; (+)-CSA / CH₂Cl₂ / 12 h / 20 °C

2: 99 percent / lipase Amano P / H₂O; diisopropyl ether / 1 h / 35 °C

With dmap; lipase Amano P; (1S)-10-camphorsulfonic acid; dicyclohexyl-carbodiimide; In dichloromethane; di-isopropyl ether; water; 1: Esterification / 2: Deacetylation;

DOI:10.1016/S0957-4166(00)00076-8

upstream raw materials:

caffeic acid

(8aS)-(+)-albicanol

3,4-diacetoxycinnamic acid

(8aS)-(+)-albicanyl acetate