(R)-diphenyl-(1-phenyl-ethyl)-phosphane oxide

Base Information

Chemical Name:(R)-diphenyl-(1-phenyl-ethyl)-phosphane oxide
CAS No.:159406-55-0
Molecular Formula:C₂₀H₁₉OP
Molecular Weight:306.344
Hs Code.:

Synonyms:(R)-diphenyl-(1-phenyl-ethyl)-phosphane oxide

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Chemical Property of (R)-diphenyl-(1-phenyl-ethyl)-phosphane oxide

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Technology Process of (R)-diphenyl-(1-phenyl-ethyl)-phosphane oxide

There total 4 articles about (R)-diphenyl-(1-phenyl-ethyl)-phosphane oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 17621-01-1
diphenyl(1-phenylethenyl)phosphine oxide

: 159406-55-0
(R)-diphenyl-(1-phenyl-ethyl)-phosphane oxide

Guidance literature:: With bis(1,5-cyclooctadiene)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen; In dichloromethane; at 20 ℃; under 37503.8 Torr; optical yield given as %ee; enantioselective reaction;

Reference yield:

: 17621-01-1
diphenyl(1-phenylethenyl)phosphine oxide

: 159406-55-0
(R)-diphenyl-(1-phenyl-ethyl)-phosphane oxide

: 55640-98-7
(S)-diphenyl-(1-phenyl-ethyl)-phosphane oxide

Guidance literature:: With C₃₂H₁₂BF₂₄^(1-)*C₅₁H₆₈IrNO₄P⁽¹⁺⁾; hydrogen; In dichloromethane; at 20 ℃; for 12h; under 37503.8 Torr; optical yield given as %ee; enantioselective reaction; Autoclave;
DOI:10.1002/chem.200903350

Reference yield:

: 4545-21-5
acetophenone p-toluenesulfonylhydrazone

: 4559-70-0
Diphenylphosphine oxide

: 159406-55-0
(R)-diphenyl-(1-phenyl-ethyl)-phosphane oxide

: 55640-98-7
(S)-diphenyl-(1-phenyl-ethyl)-phosphane oxide

Guidance literature:: With tetrakis(acetonitrile)copper(I)tetrafluoroborate; C₃₆H₃₆NO₃PS; potassium carbonate; In 1,4-dioxane; at 60 ℃; for 2h; Solvent; Reagent/catalyst; Temperature; Overall yield = 90 %; Optical yield = 28 %ee; stereoselective reaction; Catalytic behavior; Inert atmosphere;