17621-01-1Relevant articles and documents
Palladium-complex-catalyzed regioselective Markovnikov addition reaction and dehydrogenative double phosphinylation to terminal alkynes with diphenylphosphine oxide
Dobashi, Naotomo,Fuse, Kouichiro,Hoshino, Takako,Kanada, Jun,Kashiwabara, Taigo,Kobata, Chihiro,Nune, Satish Kumar,Tanaka, Masato
, p. 4669 - 4673 (2007)
Palladium-1,2-bis(diphenylphosphino)ethane complex catalyzes regioselective Markovnikov addition of diphenylphosphine oxide to terminal alkynes in propionitrile, while the use of triarylphopshines, di(o-tolyl)phenylphosphine in particular, as the ligand l
Transition metal-free and regioselective vinylation of phosphine oxides and: H -phosphinates with VBX reagents
Castoldi, Laura,Rajkiewicz, Adam A.,Olofsson, Berit
, p. 14389 - 14392 (2020/12/01)
A series of phosphine oxides and H-phosphinates were vinylated in the presence of the iodine(iii) reagents vinylbenziodoxolones (VBX), providing the corresponding alk-1-enyl phosphine oxides and alk-1-enyl phosphinates in good yields with complete chemo- and regioselectivity. The vinylation proceeds in open flask under mild and transition metal-free conditions.
Catalyst- and Oxidant-Free Desulfonative C?P Couplings for the Synthesis of Phosphine Oxides and Phosphonates
Guo, Hong-Mei,Zhou, Quan-Quan,Jiang, Xuan,Shi, De-Qing,Xiao, Wen-Jing
supporting information, p. 4141 - 4146 (2017/10/09)
An efficient and practical approach towards phosphine oxides and phosphonates has been successfully developed through the desulfonative coupling of various sulfones with secondary phosphine oxides and phosphites. This protocol features simple experimental
Iridium-N,P-ligand-catalyzed enantioselective hydrogenation of diphenylvinylphosphine oxides and vinylphosphonates
Cheruku, Pradeep,Paptchikhine, Alexander,Church, Tamara L.,Andersson, Pher G.
supporting information; experimental part, p. 8285 - 8289 (2009/12/02)
Diphenylvinylphosphine oxides and di- and trisubstituted vinylphosphonates have been employed as substrates in iridium-catalyzed asymmetric hydrogenations. Complete conversions and excellent enantioselectivities (up to and above 99percent ee) were observe