[(E)-3-Methylene-5-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-4-enylsulfanyl]-benzene

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Chemical Name:[(E)-3-Methylene-5-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-4-enylsulfanyl]-benzene
CAS No.:362049-76-1
Molecular Formula:C₂₁H₂₈S
Molecular Weight:312.519
Hs Code.:

Synonyms:[(E)-3-Methylene-5-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-4-enylsulfanyl]-benzene

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Chemical Property of [(E)-3-Methylene-5-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-4-enylsulfanyl]-benzene

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Technology Process of [(E)-3-Methylene-5-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-4-enylsulfanyl]-benzene

There total 3 articles about [(E)-3-Methylene-5-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-4-enylsulfanyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 13170-43-9
(trimethylsilyl)methylmagnesium chloride

: 362049-75-0
(E)-5-Phenylsulfanyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-1-en-3-one

: 362049-76-1
[(E)-3-Methylene-5-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-4-enylsulfanyl]-benzene

Guidance literature:: In diethyl ether; at 0 - 20 ℃; for 1.5h;
DOI:10.1016/S0040-4039(01)00845-0

Reference yield:

: 79-77-6,14901-07-6
(E)-β-ionone

: 362049-76-1
[(E)-3-Methylene-5-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-4-enylsulfanyl]-benzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: LDA / tetrahydrofuran / 0.5 h / -70 °C

1.2: 95 percent / tetrahydrofuran / 1.5 h / -70 - 0 °C

2.1: 55 percent / ZnBr₂ / CH₂Cl₂ / 12 h / 20 °C

3.1: 85 percent / diethyl ether / 1.5 h / 0 - 20 °C

With zinc dibromide; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; dichloromethane; 3.1: Peterson olefination;
DOI:10.1016/S0040-4039(01)00845-0

Reference yield:

: 79636-77-4
β-ionone

: 362049-76-1
[(E)-3-Methylene-5-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-4-enylsulfanyl]-benzene

Guidance literature:: Multi-step reaction with 2 steps

1: 55 percent / ZnBr₂ / CH₂Cl₂ / 12 h / 20 °C

2: 85 percent / diethyl ether / 1.5 h / 0 - 20 °C

With zinc dibromide; In diethyl ether; dichloromethane; 2: Peterson olefination;
DOI:10.1016/S0040-4039(01)00845-0