2,3-Dimethyl-2-nitrobutanedioate

Base Information

Chemical Name:2,3-Dimethyl-2-nitrobutanedioate
CAS No.:28081-31-4
Molecular Formula:C6H9 N O6
Molecular Weight:191.141
Hs Code.:2917190090
DSSTox Substance ID:DTXSID90700901
Mol file:28081-31-4.mol

Synonyms:DTXSID90700901;2,3-dimethyl-2-nitrobutanedioate

Suppliers and Price of 2,3-Dimethyl-2-nitrobutanedioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 2,3-Dimethyl-2-nitrobutanedioate

Chemical Property:

PSA：126.08000
LogP:-2.31910
XLogP3:1.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:1
Exact Mass:189.02733694
Heavy Atom Count:13
Complexity:245

Purity/Quality:: 98%Min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C(=O)[O-])C(C)(C(=O)[O-])[N+](=O)[O-]

Technology Process of 2,3-Dimethyl-2-nitrobutanedioate

There total 8 articles about 2,3-Dimethyl-2-nitrobutanedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 760-90-7
dimethyl 2-bromosuccinate

: 28081-31-4
dimethyl α-nitrosuccinate

Guidance literature:: With 3,5-dihydroxyphenol; sodium nitrite; In N,N-dimethyl-formamide; at 20 ℃; for 12h;
DOI:10.1021/acs.orglett.9b03894

Reference yield:

: 98298-19-2
3-bromo-4-methoxy-4-oxobutanoic acid

: 28081-31-4
dimethyl α-nitrosuccinate

Guidance literature:: Multi-step reaction with 2 steps

1: toluene-4-sulfonic acid / 12 h / 65 °C

2: sodium nitrite; 3,5-dihydroxyphenol / N,N-dimethyl-formamide / 12 h / 20 °C

With 3,5-dihydroxyphenol; toluene-4-sulfonic acid; sodium nitrite; In N,N-dimethyl-formamide;
DOI:10.1021/acs.orglett.9b03894