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2483-57-0

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2483-57-0 Usage

Chemical Properties

clear yellow liquid

Uses

Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.

Synthesis Reference(s)

The Journal of Organic Chemistry, 25, p. 266, 1960 DOI: 10.1021/jo01072a606

Check Digit Verification of cas no

The CAS Registry Mumber 2483-57-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,4,8 and 3 respectively; the second part has 2 digits, 5 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 2483-57:
(6*2)+(5*4)+(4*8)+(3*3)+(2*5)+(1*7)=90
90 % 10 = 0
So 2483-57-0 is a valid CAS Registry Number.
InChI:InChI=1/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3

2483-57-0 Well-known Company Product Price

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  • Alfa Aesar

  • (L18950)  Methyl nitroacetate, 98%   

  • 2483-57-0

  • 2g

  • 635.0CNY

  • Detail
  • Alfa Aesar

  • (L18950)  Methyl nitroacetate, 98%   

  • 2483-57-0

  • 10g

  • 2306.0CNY

  • Detail

2483-57-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name methyl 2-nitroacetate

1.2 Other means of identification

Product number -
Other names Acetic acid, nitro-, methyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2483-57-0 SDS

2483-57-0Relevant articles and documents

-

Finkbeiner,H.L.,Wagner,G.W.

, p. 215 - 217 (1963)

-

REDUCTION OF CHLORO- AND BROMONITROACETATE ESTERS

Yurtanov, A. I.,Naidovskii, E. S.,Belov, Yu. P.,Martynov, I. V.

, p. 1076 - 1077 (1987)

-

Matthews,Kubler

, p. 266,268 (1960)

First chemoenzymatic synthesis of (+)-2-carboxypyrrolidine-3-acetic acid, the nucleus of kainoid amino acids

Felluga, Fulvia,Forzato, Cristina,Nitti, Patrizia,Pitacco, Giuliana,Ghelfi, Franco,Valentin, Ennio

experimental part, p. 112 - 118 (2012/02/16)

The distinctive nucleus of kainoid amino acids, (2S,3R)-(+)-2- carboxypyrrolidine- 3-acetic acid 6, was synthesized by a chemoenzymatic process, exploiting the diastereomeric cis/ trans methyl pyroglutamate derivatives 10a-c/11a-c as key intermediates. These mixtures, when subjected to a kinetic resolution mediated by α-chymotrypsin, reacted diastereo-, regio-, and enantioselectively to give the trans derivatives (+)-10a-c possessing the correct (2S,3R) configuration. Subsequently, the desired product (2S,3R)-(+)-6 could be obtained after well-established transformations.

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