.beta.-D-Glucopyranose, 1,6-anhydro-2-deoxy-2-fluoro-4-O-(phenylmethyl)-

Base Information

Chemical Name:.beta.-D-Glucopyranose, 1,6-anhydro-2-deoxy-2-fluoro-4-O-(phenylmethyl)-
CAS No.:23094-75-9
Molecular Formula:C13H15 F O4
Molecular Weight:254.258
Hs Code.:

Synonyms:Glucopyranose,1,6-anhydro-4-O-benzyl-2-deoxy-2-fluoro-, b-D- (8CI); 6,8-Dioxabicyclo[3.2.1]octane, b-D-glucopyranose deriv.;1,6-Anhydro-4-O-benzyl-2-deoxy-2-fluoro-b-D-glucopyranose

Suppliers and Price of .beta.-D-Glucopyranose, 1,6-anhydro-2-deoxy-2-fluoro-4-O-(phenylmethyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of .beta.-D-Glucopyranose, 1,6-anhydro-2-deoxy-2-fluoro-4-O-(phenylmethyl)-

Chemical Property:

PSA：47.92000
LogP:1.02590

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of .beta.-D-Glucopyranose, 1,6-anhydro-2-deoxy-2-fluoro-4-O-(phenylmethyl)-

There total 1 articles about .beta.-D-Glucopyranose, 1,6-anhydro-2-deoxy-2-fluoro-4-O-(phenylmethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 33208-47-8
4-O-benzyl-1,6:2,3-dianhydro-β-D-mannopyranose

: 23094-75-9
1,6-anhydro-4-O-benzyl-2-deoxy-2-fluoro-β-D-glucopyranoside

Guidance literature:: With potassium fluoride; potassium hydrogen difluoride; In ethylene glycol; for 4h; Inert atmosphere;
DOI:10.1021/acs.joc.9b00795

Reference yield: 98.0%

: 23094-75-9
1,6-anhydro-4-O-benzyl-2-deoxy-2-fluoro-β-D-glucopyranoside

: 100-39-0
benzyl bromide

: 97292-03-0
1,6-Anhydro-3,4-di-O-benzyl-2-deoxy-2-fluoro-β-D-glucopyranose

Guidance literature:: With tetra-(n-butyl)ammonium iodide; sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 - 20 ℃; for 2h; Inert atmosphere;
DOI:10.1002/chem.202002825

Reference yield: 87.0%

: 23094-75-9
1,6-anhydro-4-O-benzyl-2-deoxy-2-fluoro-β-D-glucopyranoside

: 1,6-anhydro-4-O-benzyl-2,3-dideoxy-2,3-difluoro-β-D-glucopyranoside

Guidance literature:: With (bis-(2-methoxyethyl)amino)sulfur trufluoride; In tetrahydrofuran; at 100 ℃; for 1.5h; Inert atmosphere; Microwave irradiation;
DOI:10.1002/chem.201806197