2,3,4-tri-O-benzyl-1,6-bis-O-(tert-butyldimethylsilyl)hexane-1,2,3,4,5,6-hexaol

Base Information

Chemical Name:2,3,4-tri-O-benzyl-1,6-bis-O-(tert-butyldimethylsilyl)hexane-1,2,3,4,5,6-hexaol
CAS No.:898808-32-7
Molecular Formula:C₃₉H₆₀O₆Si₂
Molecular Weight:681.073
Hs Code.:

Synonyms:2,3,4-tri-O-benzyl-1,6-bis-O-(tert-butyldimethylsilyl)hexane-1,2,3,4,5,6-hexaol

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Chemical Property of 2,3,4-tri-O-benzyl-1,6-bis-O-(tert-butyldimethylsilyl)hexane-1,2,3,4,5,6-hexaol

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Technology Process of 2,3,4-tri-O-benzyl-1,6-bis-O-(tert-butyldimethylsilyl)hexane-1,2,3,4,5,6-hexaol

There total 1 articles about 2,3,4-tri-O-benzyl-1,6-bis-O-(tert-butyldimethylsilyl)hexane-1,2,3,4,5,6-hexaol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₄₀H₆₀O₅Si₂

: 898808-32-7
2,3,4-tri-O-benzyl-1,6-bis-O-(tert-butyldimethylsilyl)hexane-1,2,3,4,5,6-hexaol

: 898808-33-8
2,3,4-tri-O-benzyl-1,6-bis-O-(tert-butyldimethylsilyl)hexane-1,2,3,4,5,6-hexaol

: (2R,3R,4S,5S)-3,4,5-Tris-benzyloxy-2,6-bis-(tert-butyl-dimethyl-silanyloxy)-hexan-1-ol

Guidance literature:: C₄₀H₆₀O₅Si₂; With pyridine; ozone; In methanol; dichloromethane; at -78 ℃;

With sodium tetrahydroborate; In methanol; dichloromethane; at -78 - 20 ℃;
DOI:10.1016/j.carres.2006.03.031

Reference yield: 88.0%

: 898808-32-7
2,3,4-tri-O-benzyl-1,6-bis-O-(tert-butyldimethylsilyl)hexane-1,2,3,4,5,6-hexaol

: 100-39-0
benzyl bromide

: 898808-35-0
C₄₆H₆₆O₆Si₂

Guidance literature:: 2,3,4-tri-O-benzyl-1,6-bis-O-(tert-butyldimethylsilyl)hexane-1,2,3,4,5,6-hexaol; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 1h;

benzyl bromide; With tetra-(n-butyl)ammonium iodide; In tetrahydrofuran; at 0 - 20 ℃;
DOI:10.1016/j.carres.2006.03.031

Reference yield:

: 898808-32-7
2,3,4-tri-O-benzyl-1,6-bis-O-(tert-butyldimethylsilyl)hexane-1,2,3,4,5,6-hexaol

: 898808-36-1
(2S,3S,4S,5R)-2,3,4,5-Tetrakis-benzyloxy-hexane-1,6-diol

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / tetrahydrofuran / 1 h / 20 °C

1.2: 88 percent / TBAI / tetrahydrofuran / 0 - 20 °C

2.1: 89 percent / TBAF / tetrahydrofuran / 2 h / 20 °C

With tetrabutyl ammonium fluoride; sodium hydride; In tetrahydrofuran;
DOI:10.1016/j.carres.2006.03.031