4,4'-Bipyridinium dichloride

Base Information

• Chemical Name: 4,4'-Bipyridinium dichloride
• CAS No.: 27926-72-3
• Molecular Formula: C10H8 N2 . 2 Cl H
• Molecular Weight: 229.109
• Hs Code.: 2933399090
• European Community (EC) Number: 248-732-1
• DSSTox Substance ID: DTXSID00950617
• Mol file: 27926-72-3.mol

Synonyms:27926-72-3;4,4'-Bipyridine dihydrochloride;4,4'-Bipyridinium dichloride;4,4'-Dipyridyl dihydrochloride;4,4'-Bipyridine, dihydrochloride;4-pyridin-4-ylpyridine;dihydrochloride;4,4'-Dipyridyl DiHCl;EINECS 248-732-1;4,4'-dipyridyldihydrochloride;4,4'-Bipyridinedihydrochloride;SCHEMBL9846613;DTXSID00950617;CBA92672;MFCD00012824;AKOS024262409;4,4'-Bipyridine--hydrogen chloride (1/2);FT-0617103;D97812

Chemical Property of 4,4'-Bipyridinium dichloride

Chemical Property:

• Melting Point: >300 °C(lit.)
• Boiling Point: 497.3°Cat760mmHg
• Flash Point: 254.6°C
• PSA: 25.78000
• Density: 1.257g/cm³
• LogP: 3.74760
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 228.0221037
• Heavy Atom Count: 14
• Complexity: 108

Purity/Quality:

98%Min ^*data from raw suppliers

4,4''-BipyridineDihydrochloride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,Xi
• Statements: 23/24/25-36/37/38
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Pyridines
• Canonical SMILES: C1=CN=CC=C1C2=CC=NC=C2.Cl.Cl
• Uses: is used in manufacturing of Nitrogen-containing Carbon alloy having high Oxygen-redaction activity for fuel-cell catalyst.

Technology Process of 4,4'-Bipyridinium dichloride

There total 1 articles about 4,4'-Bipyridinium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4,4'-bipyridine (553-26-4) → 4,4'-Bipyridine dihydrochloride (27926-72-3)

Guidance literature:

With hydrogenchloride; In diethyl ether;

DOI:10.1021/cg400752y

Reference yield: 98.0%

4,4'-Bipyridine dihydrochloride (27926-72-3) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → C10H8N2*2C32H12BF24(1-)*2H(1+)

Guidance literature:

In dichloromethane; water; at 20 ℃; for 6h;

DOI:10.3762/bjoc.15.173

upstream raw materials:

4,4'-bipyridine

Refernces

• 1、 Li, Jing,Shi, Qiang,Han, Ying,Chen, Chuan-Feng. "Complexation of 2,6-helic[6]arene and its derivatives with 1,1′-dimethyl-4,4′-bipyridinium salts and protonated 4,4'-bipyridinium salts: An acid-base controllable complexation". . p. 1795 - 1804. Retrieved 2019.