5-O-tert-butyldimethylsilyl-N-diphenylmethyl-1,4-dideoxy-1,4-imino-D-lyxytol

Base Information

Chemical Name:5-O-tert-butyldimethylsilyl-N-diphenylmethyl-1,4-dideoxy-1,4-imino-D-lyxytol
CAS No.:208253-74-1
Molecular Formula:C₂₄H₃₅NO₃Si
Molecular Weight:413.632
Hs Code.:

Synonyms:5-O-tert-butyldimethylsilyl-N-diphenylmethyl-1,4-dideoxy-1,4-imino-D-lyxytol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5-O-tert-butyldimethylsilyl-N-diphenylmethyl-1,4-dideoxy-1,4-imino-D-lyxytol

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Technology Process of 5-O-tert-butyldimethylsilyl-N-diphenylmethyl-1,4-dideoxy-1,4-imino-D-lyxytol

There total 6 articles about 5-O-tert-butyldimethylsilyl-N-diphenylmethyl-1,4-dideoxy-1,4-imino-D-lyxytol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 301523-15-9
(2R,3S,4R)-N-diphenylmethyl-5-O-tert-butyldimethylsilyl-4-aminopentane-1,2,3,5-tetraol

: 208253-74-1
5-O-tert-butyldimethylsilyl-N-diphenylmethyl-1,4-dideoxy-1,4-imino-D-lyxytol

Guidance literature:: With tetrachloromethane; triethylamine; triphenylphosphine; In N,N-dimethyl-formamide; at 20 ℃; for 17h;
DOI:10.1021/jo000527u

Reference yield:

: 2,2-Dimethyl-propionic acid (1S,2R)-2-(benzhydryl-amino)-3-(tert-butyl-dimethyl-silanyloxy)-1-((R)-1,2-dihydroxy-ethyl)-propyl ester

: 208253-74-1
5-O-tert-butyldimethylsilyl-N-diphenylmethyl-1,4-dideoxy-1,4-imino-D-lyxytol

Guidance literature:: 2,2-Dimethyl-propionic acid (1S,2R)-2-(benzhydryl-amino)-3-(tert-butyl-dimethyl-silanyloxy)-1-((R)-1,2-dihydroxy-ethyl)-propyl ester; With tetrachloromethane; triethylamine; triphenylphosphine; In N,N-dimethyl-formamide; at 20 ℃;

With sodium methylate; In methanol; Further stages.;
DOI:10.1021/jo000527u

Reference yield:

: 208253-71-8
(2R,3R)-N-diphenylmethylene-1-O-tert-butyldimethylsilyl-3-O-trimethylacetyl-2-amino-4-pentene-1,2-diol

: 208253-74-1
5-O-tert-butyldimethylsilyl-N-diphenylmethyl-1,4-dideoxy-1,4-imino-D-lyxytol

Guidance literature:: Multi-step reaction with 3 steps

1: K₂Os(OH)4; K₃Fe(CN)6; K₂CO₃ / 2-methyl-propan-2-ol; H₂O / 20 °C / pH 12

2: 84 percent / LiBH₄ / tetrahydrofuran / Heating

3: 90 percent / PPh₃; CCl₄; Et₃N / dimethylformamide / 17 h / 20 °C

With tetrachloromethane; lithium borohydride; K₂Os(OH)4; potassium carbonate; triethylamine; triphenylphosphine; potassium hexacyanoferrate(III); In tetrahydrofuran; water; N,N-dimethyl-formamide; tert-butyl alcohol; 1: dihydroxylation / 2: Reduction / 3: cyclocondensation;
DOI:10.1021/jo000527u