(3-phenylpropyl)zinc chloride

Base Information

• Chemical Name: (3-phenylpropyl)zinc chloride
• CAS No.: 1133215-81-2
• Molecular Formula: C₉H₁₁ClZn
• Molecular Weight: 220.029
• Mol file: 1133215-81-2.mol

Synonyms:(3-phenylpropyl)zinc chloride

Chemical Property of (3-phenylpropyl)zinc chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (3-phenylpropyl)zinc chloride

There total 2 articles about (3-phenylpropyl)zinc chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Bromo-3-phenylpropane (637-59-2) + zinc(II) chloride (7646-85-7,24359-56-6) → (3-phenylpropyl)zinc chloride (1133215-81-2)

Guidance literature:

1-Bromo-3-phenylpropane; With magnesium; lithium chloride; In tetrahydrofuran; Inert atmosphere; Schlenk technique; Cooling with ice;

zinc(II) chloride; In tetrahydrofuran; at 0 - 20 ℃; for 0.25h; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201914490

Reference yield:

phenylpropyl chloride (104-52-9) + zinc (7440-66-6) → (3-phenylpropyl)zinc chloride (1133215-81-2)

Guidance literature:

With N,N-dimethyl acetamide; for 4h; Milling;

DOI:10.1002/anie.201806480

Reference yield: 90.0%

(3-phenylpropyl)zinc chloride (1133215-81-2) + 1,1-dichlorobut-2-yne (139185-44-7) → (6-chloro-4-methylhexa-4,5-dien-1-yl)benzene (1296846-38-2)

Guidance literature:

With copper(I) cyanide di(lithium chloride); In tetrahydrofuran; at -20 ℃; for 1h; regioselective reaction; Inert atmosphere;

DOI:10.1002/chem.201003273

upstream raw materials:

phenylpropyl chloride

zinc

1-Bromo-3-phenylpropane

zinc(II) chloride

Downstream raw materials:

2-(3-phenylpropyl)oxazole

1‐[²H]‐3‐phenylpropane

ethyl 4-(3-methyl-6-phenylhexa-1,2-dien-1-yl)benzoate

[8-chloro-4-(2-chloroethenylidene)octyl]benzene