methyl 2-O-benzoyl-6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside

Base Information

• Chemical Name: methyl 2-O-benzoyl-6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside
• CAS No.: 123076-85-7
• Molecular Formula: C₁₇H₂₂O₆
• Molecular Weight: 322.358
• Mol file: 123076-85-7.mol

Synonyms:methyl 2-O-benzoyl-6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside

Chemical Property of methyl 2-O-benzoyl-6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2-O-benzoyl-6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside

There total 3 articles about methyl 2-O-benzoyl-6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

methyl 6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside (39981-26-5) + benzoyl chloride (98-88-4) → methyl 2-O-benzoyl-6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside (123076-85-7)

Guidance literature:

With pyridine; for 1h;

DOI:10.1002/ejoc.200701173

Reference yield: 71.0%

methyl 6-deoxy-6-iodo-3,4-O-isopropylidene-β-D-galactopyranoside (95120-18-6) + benzoyl chloride (98-88-4) → methyl 2-O-benzoyl-6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside (123076-85-7)

Guidance literature:

methyl 6-deoxy-6-iodo-3,4-O-isopropylidene-β-D-galactopyranoside; With hydrogen; diethylamine; palladium on activated charcoal; In ethyl acetate; Petroleum ether;

benzoyl chloride; With triethylamine; In dichloromethane;

DOI:10.1071/CH03203

Reference yield:

methyl 6-deoxy-3,4-O-isopropylidene-D-galactopyranoside (14917-69-2,17014-02-7,24577-96-6,39981-26-5,63848-11-3,65310-01-2,71772-35-5,72904-81-5,124264-65-9,135029-35-5) + benzoyl chloride (98-88-4) → methyl 2-O-benzoyl-6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside (123076-85-7) + methyl 2-O-benzoyl-6-deoxy-3,4-O-isopropylidene-α-D-galactopyranoside (123076-84-6)

Guidance literature:

With pyridine; for 1.5h; Ambient temperature;

DOI:10.1021/jo00278a035

upstream raw materials:

methyl 6-deoxy-3,4-O-isopropylidene-D-galactopyranoside

benzoyl chloride

methyl 6-deoxy-6-iodo-3,4-O-isopropylidene-β-D-galactopyranoside

methyl 6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside

Downstream raw materials:

methyl 2-O-benzoyl-6-deoxy-β-D-galactopyranoside

methyl 4-O-acetyl-2-O-benzoyl-3,6-dideoxy-3-<2-(p-tolylsulfonyl)hydrazino>-β-D-galactopyranoside

methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-β-D-xylo-hexopyranosid-3-ulose (p-tolylsulfonyl)hydrazone

methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-β-D-xylo-hexopyranosid-3-ulose