Hexanediol monovinyl ether

Base Information

• Chemical Name: Hexanediol monovinyl ether
• CAS No.: 27336-16-9
• Molecular Formula: C8H16 O2
• Molecular Weight: 144.214
• Hs Code.: 2909499000
• Mol file: 27336-16-9.mol

Synonyms:1-Hexanol,6-(vinyloxy)- (8CI); 1,6-Hexanediol monovinyl ether; 6-(Vinyloxy)hexanol;6-Hydroxyhexyl vinyl ether

Chemical Property of Hexanediol monovinyl ether

Chemical Property:

• Vapor Pressure: 0.028mmHg at 25°C
• Refractive Index: 1.441
• Boiling Point: 217.77°C at 760 mmHg
• Flash Point: 79.705°C
• PSA: 29.46000
• Density: 0.904g/cm³
• LogP: 2.04520

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Hexanediol monovinyl ether

There total 4 articles about Hexanediol monovinyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

vinyl acetate (108-05-4,9003-20-7) + 1,6-hexanediol (629-11-8) → 6-vinyloxy-1-hexanol (27336-16-9) + 1,6-bis(vinyloxy)hexane (19763-13-4)

Guidance literature:

With bis(1,5-cyclooctadiene)diiridium(I) dichloride; sodium acetate; In toluene; at 100 ℃; for 6h;

DOI:10.1021/ja0173932

Reference yield: 19.0%

-butyl vinyl ether (111-34-2,92680-80-3) + 1,6-hexanediol (629-11-8) → 6-vinyloxy-1-hexanol (27336-16-9) + 1,6-bis(vinyloxy)hexane (19763-13-4)

Guidance literature:

With palladium; bathophenanthroline; sodium acetate; In methanol; at 120 ℃; for 24h; Temperature; Catalytic behavior; Schlenk technique;

Reference yield:

1,6-hexanediol (629-11-8) + ethyl vinyl ether (109-92-2,25104-37-4) → 6-vinyloxy-1-hexanol (27336-16-9) + 1,6-bis(vinyloxy)hexane (19763-13-4)

Guidance literature:

With silver(I) acetate; (triphenylphosphine)gold(I) chloride; at 50 ℃; for 12h;

DOI:10.1016/j.tetlet.2008.04.037

upstream raw materials:

vinyl acetate

1,6-hexanediol

ethyl vinyl ether

-butyl vinyl ether