(Z)-2-heptylidene-3-methylene-1,5-ditosyl-1,5-diazocane

Base Information

Chemical Name:(Z)-2-heptylidene-3-methylene-1,5-ditosyl-1,5-diazocane
CAS No.:1443365-75-0
Molecular Formula:C₂₈H₃₈N₂O₄S₂
Molecular Weight:530.753
Hs Code.:

Synonyms:(Z)-2-heptylidene-3-methylene-1,5-ditosyl-1,5-diazocane

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Chemical Property of (Z)-2-heptylidene-3-methylene-1,5-ditosyl-1,5-diazocane

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Technology Process of (Z)-2-heptylidene-3-methylene-1,5-ditosyl-1,5-diazocane

There total 6 articles about (Z)-2-heptylidene-3-methylene-1,5-ditosyl-1,5-diazocane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 1443365-63-6
N-(2-bromoallyl)-4-methyl-N-(3-(4-methyl-N-(oct-1-yn-1-yl)phenylsulfonamido)propyl)benzenesulfonamide

: 1443365-75-0
(Z)-2-heptylidene-3-methylene-1,5-ditosyl-1,5-diazocane

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydrogencarbonate; In ethanol; at 80 ℃; for 20h;
DOI:10.1002/adsc.201200703

Reference yield:

: 98-59-9
p-toluenesulfonyl chloride

: 1443365-75-0
(Z)-2-heptylidene-3-methylene-1,5-ditosyl-1,5-diazocane

Guidance literature:: Multi-step reaction with 6 steps

1: triethylamine / dichloromethane

2: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran

3: sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; tetra-(n-butyl)ammonium iodide / water; toluene

4: trifluoroacetic acid / dichloromethane / 0 °C

5: 1,10-Phenanthroline; potassium phosphate; copper(ll) sulfate pentahydrate / toluene / 48 h / 85 °C

6: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydrogencarbonate / ethanol / 20 h / 80 °C

With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 1,10-Phenanthroline; copper(ll) sulfate pentahydrate; di-isopropyl azodicarboxylate; tetra(n-butyl)ammonium hydrogensulfate; tetra-(n-butyl)ammonium iodide; sodium hydrogencarbonate; triethylamine; triphenylphosphine; trifluoroacetic acid; sodium hydroxide; In tetrahydrofuran; ethanol; dichloromethane; water; toluene;
DOI:10.1002/adsc.201200703

Reference yield:

: 176107-53-2
N,N'-bis(p-toluenesulfonamido)-N-(tert-butoxycarbonyl)-1,3-propanediamine

: 1443365-75-0
(Z)-2-heptylidene-3-methylene-1,5-ditosyl-1,5-diazocane

Guidance literature:: Multi-step reaction with 4 steps

1: sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; tetra-(n-butyl)ammonium iodide / water; toluene

2: trifluoroacetic acid / dichloromethane / 0 °C

3: 1,10-Phenanthroline; potassium phosphate; copper(ll) sulfate pentahydrate / toluene / 48 h / 85 °C

4: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydrogencarbonate / ethanol / 20 h / 80 °C

With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 1,10-Phenanthroline; copper(ll) sulfate pentahydrate; tetra(n-butyl)ammonium hydrogensulfate; tetra-(n-butyl)ammonium iodide; sodium hydrogencarbonate; trifluoroacetic acid; sodium hydroxide; In ethanol; dichloromethane; water; toluene;
DOI:10.1002/adsc.201200703