Fe(((C₄H₉)3C₆H₂)2P₂)(CO)4

Base Information

• Chemical Name: Fe(((C₄H₉)3C₆H₂)2P₂)(CO)4
• CAS No.: 87937-39-1
• Molecular Formula: C₄₀H₅₈FeO₄P₂
• Molecular Weight: 720.693
• Mol file: 87937-39-1.mol

Synonyms:Fe(((C₄H₉)3C₆H₂)2P₂)(CO)4

Chemical Property of Fe(((C₄H₉)3C₆H₂)2P₂)(CO)4

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Fe(((C₄H₉)3C₆H₂)2P₂)(CO)4

There total 4 articles about Fe(((C₄H₉)3C₆H₂)2P₂)(CO)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

diiron nonacarbonyl (15321-51-4) + Bis(2,4,6-tri-tert-butylphenyl)diphosphen (83466-54-0,93602-74-5,79073-99-7) → Fe(((C4H9)3C6H2)2P2)(CO)4 (87937-39-1)

Guidance literature:

In hexane; (N2); the diphosphene (1.02 mmol) and Fe2(CO)9 (1.4 mmol) dissolved in hexane at 0 °C; soln. stirred for 6 h and allowed to warm to roomtemp.; (N2); concn.; filtration (Celite/n-hexane); column chromy. (silica gel,n-hexane, -40 °C); concn.; cooling to -20 °C giving crystals; mass spectrum (mol. peak);

DOI:10.1021/om00085a014

Reference yield: 65.0%

diiron nonacarbonyl (15321-51-4) + bis(2,4,6-tri-tert-butylphenyl)diphosphene (79073-99-7) → Fe(((C4H9)3C6H2)2P2)(CO)4 (87937-39-1)

Guidance literature:

In hexane; ligand treated with complex at 0°C in hexane, allowed to warm toroom temp., stirred for 6 h; filtered, pumped (vac.), chromd. (hexane) at -78°C;

DOI:10.1021/ja00364a051

Reference yield:

disodium tetracarbonylferrate + 2,4,6-tri-t-butylphenylphosphonous dichloride (79074-00-3) → Fe(((C4H9)3C6H2)2P2)(CO)4 (87937-39-1)

Guidance literature:

In tetrahydrofuran; byproducts: (2,4,6-t-Bu3C6H2)2P2;

DOI:10.1021/ja00364a051

upstream raw materials:

2,4,6-tri-t-butylphenylphosphonous dichloride

diiron nonacarbonyl

Bis(2,4,6-tri-tert-butylphenyl)diphosphen

bis(2,4,6-tri-tert-butylphenyl)diphosphene