1,2-Bis<2-amino>-5-(diazoacetyl)phenoxy>ethane

Base Information

Chemical Name:1,2-Bis<2-amino>-5-(diazoacetyl)phenoxy>ethane
CAS No.:123330-98-3
Molecular Formula:C₃₀H₃₂N₆O₁₂
Molecular Weight:668.617
Hs Code.:

1,2-Bis<2-<bis<(methoxycarbonyl)methyl>amino>-5-(diazoacetyl)phenoxy>ethane

Synonyms:1,2-Bis<2-amino>-5-(diazoacetyl)phenoxy>ethane

Suppliers and Price of 1,2-Bis<2-amino>-5-(diazoacetyl)phenoxy>ethane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,2-Bis<2-amino>-5-(diazoacetyl)phenoxy>ethane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,2-Bis<2-amino>-5-(diazoacetyl)phenoxy>ethane

There total 10 articles about 1,2-Bis<2-amino>-5-(diazoacetyl)phenoxy>ethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 619-14-7
3-hydroxy-4-nitro-benzoic acid

: 123330-98-3
1,2-Bis<2-amino>-5-(diazoacetyl)phenoxy>ethane

Guidance literature:: Multi-step reaction with 10 steps

1: 1.) pyridine; 2.) H₂O / 1.) 100 deg C, 30 min

2: SOCl₂, DMF / 0.25 h / Heating

3: pyridine / CHCl₃ / Heating

4: 45percent aq. KOH / methanol / 0.5 h

5: 1.) K₂CO₃, N-methylpyrrolidone / 1.) 125 deg C; 2.) 50 min

6: 95 percent / H₂ / 5percent Pd/C / ethyl acetate; ethanol / 1 h / Ambient temperature

7: 64 percent / 1,8-bis(dimethylamino)naphthalene / 120 h / 125 °C

8: CF₃COOH / CH₂Cl₂ / Ambient temperature

9: oxalyl chloride, DMF / CH₂Cl₂ / 0.25 h / Heating

10: CH₂Cl₂; diethyl ether / Ambient temperature

With pyridine; 1-methyl-pyrrolidin-2-one; potassium hydroxide; thionyl chloride; oxalyl dichloride; water; hydrogen; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; potassium carbonate; N,N-dimethyl-formamide; trifluoroacetic acid; palladium on activated charcoal; In methanol; diethyl ether; ethanol; dichloromethane; chloroform; ethyl acetate;
DOI:10.1021/ja00202a042

Reference yield:

: 51257-24-0
3-Acetoxy-4-Nitrobenzoic Acid

: 123330-98-3
1,2-Bis<2-amino>-5-(diazoacetyl)phenoxy>ethane

Guidance literature:: Multi-step reaction with 9 steps

1: SOCl₂, DMF / 0.25 h / Heating

2: pyridine / CHCl₃ / Heating

3: 45percent aq. KOH / methanol / 0.5 h

4: 1.) K₂CO₃, N-methylpyrrolidone / 1.) 125 deg C; 2.) 50 min

5: 95 percent / H₂ / 5percent Pd/C / ethyl acetate; ethanol / 1 h / Ambient temperature

6: 64 percent / 1,8-bis(dimethylamino)naphthalene / 120 h / 125 °C

7: CF₃COOH / CH₂Cl₂ / Ambient temperature

8: oxalyl chloride, DMF / CH₂Cl₂ / 0.25 h / Heating

9: CH₂Cl₂; diethyl ether / Ambient temperature

With pyridine; 1-methyl-pyrrolidin-2-one; potassium hydroxide; thionyl chloride; oxalyl dichloride; hydrogen; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; potassium carbonate; N,N-dimethyl-formamide; trifluoroacetic acid; palladium on activated charcoal; In methanol; diethyl ether; ethanol; dichloromethane; chloroform; ethyl acetate;
DOI:10.1021/ja00202a042

Reference yield:

: 123330-86-9
tert-Butyl 3-hydroxy-4-nitrobenzoate

: 123330-98-3
1,2-Bis<2-amino>-5-(diazoacetyl)phenoxy>ethane

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) K₂CO₃, N-methylpyrrolidone / 1.) 125 deg C; 2.) 50 min

2: 95 percent / H₂ / 5percent Pd/C / ethyl acetate; ethanol / 1 h / Ambient temperature

3: 64 percent / 1,8-bis(dimethylamino)naphthalene / 120 h / 125 °C

4: CF₃COOH / CH₂Cl₂ / Ambient temperature

5: oxalyl chloride, DMF / CH₂Cl₂ / 0.25 h / Heating

6: CH₂Cl₂; diethyl ether / Ambient temperature

With 1-methyl-pyrrolidin-2-one; oxalyl dichloride; hydrogen; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; potassium carbonate; N,N-dimethyl-formamide; trifluoroacetic acid; palladium on activated charcoal; In diethyl ether; ethanol; dichloromethane; ethyl acetate;
DOI:10.1021/ja00202a042