2-(3-Pentynyl)-2-methyl-1,3-dioxolane

Base Information

Chemical Name:2-(3-Pentynyl)-2-methyl-1,3-dioxolane
CAS No.:22592-16-1
Molecular Formula:C₉H₁₄O₂
Molecular Weight:154.209
Hs Code.:
DSSTox Substance ID:DTXSID901276445
Nikkaji Number:J482.212I
Mol file:22592-16-1.mol

Synonyms:22592-16-1;DTXSID901276445;2-(3-Pentynyl)-2-methyl-1,3-dioxolane;2-Methyl-2-(3-pentyn-1-yl)-1,3-dioxolane;1,3-Dioxolane,2-methyl-2-(3-pentynyl)-(7ci,8ci,9ci)

Suppliers and Price of 2-(3-Pentynyl)-2-methyl-1,3-dioxolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 2-(3-Pentynyl)-2-methyl-1,3-dioxolane

Chemical Property:

Boiling Point:97 °C (13 mmHg)
PSA：18.46000
LogP:1.55290
XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:154.099379685
Heavy Atom Count:11
Complexity:178

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC#CCCC1(OCCO1)C

Technology Process of 2-(3-Pentynyl)-2-methyl-1,3-dioxolane

There total 3 articles about 2-(3-Pentynyl)-2-methyl-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 42541-87-7
2-(but-3'-ynyl)-2-methyl-1,3-dioxolane

: 74-88-4
methyl iodide

: 22592-16-1
2-(ethylenedioxy)-5-heptyne

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; 1.) -78 deg C, 30 min, 2.) -78 deg C, 3 h; 25 deg C, 2 h;
DOI:10.1021/jo00107a011

Reference yield:

: 2550-28-9
5-hexyn-2-one

: 22592-16-1
2-(ethylenedioxy)-5-heptyne

Guidance literature:: Multi-step reaction with 2 steps

1: trimethyl orthoformate, p-TsOH / 2 h

2: 87 percent / BuLi / tetrahydrofuran; hexane / 1.) -78 deg C, 30 min, 2.) -78 deg C, 3 h; 25 deg C, 2 h

With n-butyllithium; toluene-4-sulfonic acid; trimethyl orthoformate; In tetrahydrofuran; hexane;
DOI:10.1021/jo00107a011