Ethyl (2E)-2-[(acetyloxy)methyl]-2-butenoate

Base Information

Chemical Name:Ethyl (2E)-2-[(acetyloxy)methyl]-2-butenoate
CAS No.:7691-31-8
Molecular Formula:C₉H₁₄O₄
Molecular Weight:186.208
Hs Code.:
DSSTox Substance ID:DTXSID501259669
Nikkaji Number:J2.941.248K

Synonyms:DTXSID501259669;7691-31-8;Ethyl (2E)-2-[(acetyloxy)methyl]-2-butenoate

Suppliers and Price of Ethyl (2E)-2-[(acetyloxy)methyl]-2-butenoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Ethyl (2E)-2-[(acetyloxy)methyl]-2-butenoate

Chemical Property:

XLogP3:1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:186.08920892
Heavy Atom Count:13
Complexity:218

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCOC(=O)C(=CC)COC(=O)C
Isomeric SMILES:CCOC(=O)/C(=C/C)/COC(=O)C

Technology Process of Ethyl (2E)-2-[(acetyloxy)methyl]-2-butenoate

There total 1 articles about Ethyl (2E)-2-[(acetyloxy)methyl]-2-butenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 5717-41-9
ethyl 2-methylbuta-2,3-dienoate

: 64-19-7,77671-22-8
acetic acid

: 7691-31-8
2-Acetoxymethyl-but-2-ensaeureethylester

: 58683-54-8
diethyl 4-vinylcyclohex-1-ene-1,4-dicarboxylate

Guidance literature:: With triphenylphosphine; In chloroform; at 20 ℃; for 12h; optical yield given as %de; stereoselective reaction;
DOI:10.1021/jo201466k

Reference yield:

: 7691-31-8
2-Acetoxymethyl-but-2-ensaeureethylester

: 512-74-3,122131-78-6,159517-28-9
Mikanecinsaeure

Guidance literature:: Multi-step reaction with 2 steps

1: Ba(OH)2 / aq. ethanol / Heating

2: aq. NaOH / Heating

With barium dihydroxide; sodium hydroxide; In ethanol;
DOI:10.1021/jo01277a069