2-[1,5-anhydro-2-deoxy-4,6-O-(di-tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabinohex-1-enitol-3,5-bis(benzyloxy)]-benzyl alcohol

Base Information

Chemical Name:2-[1,5-anhydro-2-deoxy-4,6-O-(di-tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabinohex-1-enitol-3,5-bis(benzyloxy)]-benzyl alcohol
CAS No.:1392097-98-1
Molecular Formula:C₄₄H₆₄O₇Si₂
Molecular Weight:761.159
Hs Code.:

Synonyms:2-[1,5-anhydro-2-deoxy-4,6-O-(di-tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabinohex-1-enitol-3,5-bis(benzyloxy)]-benzyl alcohol

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Chemical Property of 2-[1,5-anhydro-2-deoxy-4,6-O-(di-tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabinohex-1-enitol-3,5-bis(benzyloxy)]-benzyl alcohol

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Technology Process of 2-[1,5-anhydro-2-deoxy-4,6-O-(di-tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabinohex-1-enitol-3,5-bis(benzyloxy)]-benzyl alcohol

There total 13 articles about 2-[1,5-anhydro-2-deoxy-4,6-O-(di-tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabinohex-1-enitol-3,5-bis(benzyloxy)]-benzyl alcohol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 934243-80-8
2-iodo-3,5-bis(phenylmethoxy)benzenemethanol

: 842132-50-7
1,5-anhydro-2-deoxy-4,6-O-di-(tert-butyl)silanediyl-3-O-triisopropylsilyl-D-arabino-hex-1-enitolylboronic acid pinacol ester

: 1392097-98-1
2-[1,5-anhydro-2-deoxy-4,6-O-(di-tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabinohex-1-enitol-3,5-bis(benzyloxy)]-benzyl alcohol

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate; In 1,2-dimethoxyethane; water; at 60 ℃; for 12h; Inert atmosphere;
DOI:10.1002/chem.201304304

Reference yield: 86.0%

: 1392097-95-8
C₄₉H₇₂O₈Si₂

: 1392097-98-1
2-[1,5-anhydro-2-deoxy-4,6-O-(di-tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabinohex-1-enitol-3,5-bis(benzyloxy)]-benzyl alcohol

Guidance literature:: With diisobutylaluminium hydride; In hexane; dichloromethane; at -78 - 20 ℃; for 1.08333h; Inert atmosphere;
DOI:10.3762/bjoc.8.82

Reference yield:

: 191593-14-3
4,6-O-di(tert-butyl)silanediyl-D-glucal

: 1392097-98-1
2-[1,5-anhydro-2-deoxy-4,6-O-(di-tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabinohex-1-enitol-3,5-bis(benzyloxy)]-benzyl alcohol

Guidance literature:: Multi-step reaction with 5 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 68 h / 20 - 60 °C / Inert atmosphere

2.1: tert.-butyl lithium / diethyl ether; pentane / 2 h / -78 - 0 °C / Inert atmosphere

2.2: 1 h / -78 - 20 °C / Inert atmosphere

3.1: [RhCl₂(p-cymene)]2; water / acetonitrile; benzene / 4 h / 20 °C

4.1: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium t-butanolate / toluene / Inert atmosphere

4.2: 6 h / 50 °C / Inert atmosphere

5.1: diisobutylaluminium hydride / hexane; dichloromethane / 1.08 h / -78 - 20 °C / Inert atmosphere

With 1H-imidazole; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; [RhCl₂(p-cymene)]2; water; tert.-butyl lithium; diisobutylaluminium hydride; sodium t-butanolate; In diethyl ether; hexane; dichloromethane; N,N-dimethyl-formamide; toluene; acetonitrile; pentane; benzene;
DOI:10.3762/bjoc.8.82