[(bis(2-diphenylphosphino-phenyl)ether)(2,9-dimethyl-1,10-phenanthroline)copper(I)] tetrafluoroborate

Base Information

• Chemical Name: [(bis(2-diphenylphosphino-phenyl)ether)(2,9-dimethyl-1,10-phenanthroline)copper(I)] tetrafluoroborate
• CAS No.: 396723-75-4
• Molecular Formula: BF₄*C₅₀H₄₀CuN₂OP₂
• Molecular Weight: 897.179
• Mol file: 396723-75-4.mol

Synonyms:[(bis(2-diphenylphosphino-phenyl)ether)(2,9-dimethyl-1,10-phenanthroline)copper(I)] tetrafluoroborate

Chemical Property of [(bis(2-diphenylphosphino-phenyl)ether)(2,9-dimethyl-1,10-phenanthroline)copper(I)] tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(bis(2-diphenylphosphino-phenyl)ether)(2,9-dimethyl-1,10-phenanthroline)copper(I)] tetrafluoroborate

There total 1 articles about [(bis(2-diphenylphosphino-phenyl)ether)(2,9-dimethyl-1,10-phenanthroline)copper(I)] tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + 2.9-dimethyl-1,10-phenanthroline (484-11-7) + bis[2-(diphenylphosphino)phenyl] ether (166330-10-5) → [(bis(2-diphenylphosphino-phenyl)ether)(2,9-dimethyl-1,10-phenanthroline)copper(I)] tetrafluoroborate (396723-75-4)

Guidance literature:

tetrakis(acetonitrile)copper(I)tetrafluoroborate; bis[2-(diphenylphosphino)phenyl] ether; In dichloromethane; at 20 ℃; for 1h;

2.9-dimethyl-1,10-phenanthroline; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1002/anie.201800144

Reference yield: 64.0%

[(bis(2-diphenylphosphino-phenyl)ether)(2,9-dimethyl-1,10-phenanthroline)copper(I)] tetrafluoroborate (396723-75-4) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → [Cu(bis[2-(diphenylphosphino)phenyl]ether)(2,9-dimethyl-1,10-phenanthroline)](tetrakis(bis-3,5-trifluoromethylphenyl)borate) (1251536-84-1)

Guidance literature:

In methanol; Na salt added to a soln. of Cu complex; pptd. (H2O), filtered, dried (vac.);

DOI:10.1021/ja103112m

upstream raw materials:

2.9-dimethyl-1,10-phenanthroline

bis[2-(diphenylphosphino)phenyl] ether

Downstream raw materials:

[Cu(bis[2-(diphenylphosphino)phenyl]ether)(2,9-dimethyl-1,10-phenanthroline)](tetrakis(bis-3,5-trifluoromethylphenyl)borate)