benzyl 3-methoxyphenyl carbonate

Base Information

• Chemical Name: benzyl 3-methoxyphenyl carbonate
• CAS No.: 1023285-98-4
• Molecular Formula: C₁₅H₁₄O₄
• Molecular Weight: 258.274
• Mol file: 1023285-98-4.mol

Synonyms:benzyl 3-methoxyphenyl carbonate

Chemical Property of benzyl 3-methoxyphenyl carbonate

Chemical Property:

Purity/Quality:

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Technology Process of benzyl 3-methoxyphenyl carbonate

There total 1 articles about benzyl 3-methoxyphenyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

O-methylresorcine (150-19-6) + benzyl chloroformate (501-53-1,94274-21-2) → benzyl 3-methoxyphenyl carbonate (1023285-98-4)

Guidance literature:

With pyridine; dmap; In dichloromethane; at 20 ℃; for 15.1667h;

DOI:10.1021/ol800548t

Reference yield: 94.0%

benzyl 3-methoxyphenyl carbonate (1023285-98-4) → 3-benzyloxyanisole (21144-16-1)

Guidance literature:

With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether; In toluene; at 60 ℃; for 3.08333h; Inert atmosphere;

DOI:10.1021/ol800548t

Reference yield:

benzyl 3-methoxyphenyl carbonate (1023285-98-4) + dimethyl pyrrolidine-2-phosphonate (869855-90-3) → (R)-dimethyl N-(benzyloxycarbonyl)pyrrolidine-2-phosphonate (1446422-46-3) + (S)-dimethyl N-(benzyloxycarbonyl)pyrrolidine-2-phosphonate + (S)-dimethyl pyrrolidine-2-phosphonate

Guidance literature:

With Candida antarctica lipase type A, immobilized NZL-101; In tert-butyl methyl ether; at 30 ℃; for 84h; Solvent; enantioselective reaction; Inert atmosphere; Enzymatic reaction;

DOI:10.1016/j.tetasy.2015.10.016

upstream raw materials:

O-methylresorcine

benzyl chloroformate

Downstream raw materials:

3-benzyloxyanisole

(R)-dimethyl N-(benzyloxycarbonyl)pyrrolidine-2-phosphonate