HEXYL ACRYLATE POLYMER

Base Information

• Chemical Name: HEXYL ACRYLATE POLYMER
• CAS No.: 27103-47-5
• Molecular Formula: C9H16O2
• Molecular Weight: 156.23
• Mol file: 27103-47-5.mol

Synonyms:POLY(N-HEXYL ACRYLATE);POLY(HEXYL ACRYLATE);HEXYL ACRYLATE POLYMER;Poly(hexyl acrylate) (20% in toluene);Polyhexylacrylateintoluene

Chemical Property of HEXYL ACRYLATE POLYMER

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Statements: 11-36/37/38
• Safety Statements: 16-29-33-36/37/39

MSDS Files:

Useful:

Technology Process of HEXYL ACRYLATE POLYMER

There total 13 articles about HEXYL ACRYLATE POLYMER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

hexyl 2-propenyl ether (3295-94-1) → n-hexyl acrylate (2499-95-8,27103-47-5)

Guidance literature:

With tert.-butylhydroperoxide; [bis(acetoxy)iodo]benzene; magnesium acetate; In decane; butyl butyrate; at 0 ℃; chemoselective reaction;

DOI:10.1016/j.tet.2011.10.112

Reference yield: 83.4%

acryloyl chloride (814-68-6,25189-84-8) + hexan-1-ol (111-27-3) → n-hexyl acrylate (2499-95-8,27103-47-5)

Guidance literature:

In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1002/chem.201504870

Reference yield: 74.0%

acrylic acid-6-iodohexyl ester (133122-99-3) → n-hexyl acrylate (2499-95-8,27103-47-5) + 1,11-dioxacycloisocosane (797-29-5) + oxecan-2-one (6008-27-1)

Guidance literature:

With sodium cyanoborohydride; In methanol; for 3h; Yields of byproduct given; Ambient temperature; Irradiation;

DOI:10.1246/cl.1994.1789

upstream raw materials:

acrylic acid methyl ester

hexan-1-ol

acrylic acid

acryloyl chloride

Refernces

• 1、 Wong, Kong Ching,Ng, Elvis,Wong, Wing-Tak,Chiu, Pauline. "Copper Hydride Catalyzed Reductive Claisen Rearrangements". supporting information. p. 3709 - 3712. Retrieved 2016/03/08.
• 2、 Sastraruji, Thanapat,Pyne, Stephen G.,Ung, Alison T.. "Oxidation of acyclic alkenes and allyl and benzyl ethers with DIB/t-BuOOH/Mg(OAc)2". experimental part. p. 598 - 602. Retrieved 2012/01/05.